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On-Demand Electrochemical Synthesis of Tetrakisacetonitrile Copper(I) Triflate and Its Application in the Aerobic Oxidation of Alcohols. | LitMetric

AI Article Synopsis

  • - The text discusses a new method for producing copper(I) triflate using an electrochemical process, which can be done in both batch and continuous flow settings.
  • - This method is advantageous because it produces only hydrogen gas as a byproduct, eliminating the need for additional purification steps.
  • - After the synthesis, the resulting solutions can be directly used for catalyzing the oxidation of benzyl alcohol without any required workup, streamlining the overall process.

Article Abstract

An on-demand electrochemical synthesis of copper(I) triflate under both batch and continuous flow conditions has been developed. A major benefit of the electrochemical methodology is that the only byproduct of the reaction is hydrogen gas, which obviates the need for workup and purification, and water is not incorporated into the product. Upon completion of the electrochemical synthesis, solutions are directly transferred or dispensed into reaction mixtures for the catalytic oxidation of benzyl alcohol with no requirement for workup or purification.

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Source
http://dx.doi.org/10.1021/acs.inorgchem.1c00488DOI Listing

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