AI Article Synopsis
- The study focuses on the synthesis and characterization of platinum dihalogenide complexes, specifically those formulated as [PtHalL], using various 10-(aryl)phenoxarsine ligands.
- Structural analysis and isomerism in solutions were examined through techniques like NMR spectroscopy and X-ray analysis.
- Under UV light, the platinum diiodide trans complexes showed a strong orange-red emission, linked to a metal halide-centered triplet state, with their optical properties further analyzed with computational methods.
Article Abstract
Synthesis and structural and photophysical characterization of platinum dihalogenide complexes formulated as [PtHalL], where Hal = Cl and I, with different 10-(aryl)phenoxarsine ligands such as 10-(-chlorophenyl)phenoxarsine, 10-(-tolyl)phenoxarsine, and 10-(phenyl)phenoxarsine are reported. The structures of complexes were determined by NMR spectroscopy, mass spectrometry, and X-ray analysis. Cis/trans isomerism of the complexes in solution was studied by NMR spectroscopy. In the solid state, under UV irradiation, platinum diiodide trans complexes exhibit an intense orange-red emission, which was attributed to a metal halide-centered triplet state. The UV/vis absorption and emission properties were studied and rationalized by density functional theory (DFT) and time-dependent DFT calculations.
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| http://dx.doi.org/10.1021/acs.inorgchem.1c00672 | DOI Listing |
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