Reaction of SeO , tetramethylammonium (TMA) chloride, aqueous HCl and Cl yields oxochloroselenate with incorporated Cl units, TMA {[Se O Cl ](Cl )}. The main feature of this compound is the strong (up to 3.5 kcal mol , according to DFT calculations) Cl⋅⋅⋅Cl bonding, which is also detected by Raman spectroscopy.
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