This article presents a study of the interfacial properties of oil-in-water emulsions containing sugar esters and polysaccharides. Sucrose fatty acid esters were synthesized using immobilized Candida antarctica lipase B. A yield of 53.4% was obtained using 2-methyl-2-butanol and 1:3 M ratio of sucrose:stearic acid. Equilibrium surface tension was 45 mN/m and low critical micellar concentration (CMC) value was obtained (ca. 10 mg/mL), characteristic of non-ionic surfactant. The interfacial properties of mixtures of sucrose esters and polysaccharides, at the oil-water interface were determined using a pendant drop tensiometer. Addition of polysaccharides increased the interfacial tension. Studies of interfacial viscoelasticity showed that the films were predominantly elastic. The presence of polysaccharides in emulsions resulted in flocculated droplets. All the emulsions presented great stability along 28 days with no creaming formation.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1016/j.foodchem.2021.129693 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
City University of Hong Kong, Chemistry, HONG KONG.
Achieving rational control over chemical and energetic properties at the perovskite/electron transport layer (ETL) interface is crucial for realizing highly efficient and stable next-generation inverted perovskite solar cells (PSCs). To address this, we developed multifunctional ferrocene (Fc)-based interlayers engineered to exhibit adjustable passivating and electrochemical characteristics. These interlayers are designed to minimize non-radiative recombination and, to modulate the work function (WF) and uniformity of the perovskite surface, thereby enhancing device performance.
View Article and Find Full Text PDFInorg Chem
January 2025
School of Chemistry and Chemical Engineering, School of Pharmacy, Jiangsu University, Zhenjiang 212013, P. R. China.
Electrochemical water splitting is a promising method for the generation of "green hydrogen", a renewable and sustainable energy source. However, the complex, multistep synthesis processes, often involving hazardous or expensive chemicals, limit its broader adoption. Herein, a nitrate (NO) anion-intercalated nickel-iron-cerium mixed-metal (oxy)hydroxide heterostructure electrocatalyst is fabricated on nickel foam (NiFeCeOH@NF) via a simple electrodeposition method followed by cyclic voltammetry activation to enhance its surface properties.
View Article and Find Full Text PDFNanoscale
January 2025
Photon Science Research Center for Carbon Dioxide, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China.
Oxygen vacancies (V's) are of paramount importance in influencing the properties and applications of ceria (CeO). Yet, comprehending the distribution and nature of V's poses a significant challenge due to the vast number of electronic configurations and intricate many-body interactions among V's and polarons (Ce ions). In this study, we established a cluster expansion model based on first-principles calculations and statistical learning to decouple the interactions among the Ce ions and V's, thereby circumventing the limitations associated with sampling electronic configurations.
View Article and Find Full Text PDFJ Phys Chem B
January 2025
Department of Computer and Information Sciences, Department of Materials Science and Engineering, University of Delaware, Newark, Delaware 19716, United States.
Liquid phase-separating proteins can form condensates that play an important role in spatial and temporal organization of biological cells. The understanding of the mechanisms that lead to the formation of protein condensates and their interactions with other biomolecules may lead to processing routes for soft materials with tailored geometry and function. Fused in sarcoma (FUS) is an example of a nuclear protein that forms stable complexes, and recent studies have highlighted its ability to wet actin filaments and bundle them into networks.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Centre of Climate Studies, Indian Institute of Technology Bombay, Mumbai 400076, Maharashtra, India.
The immense energy footprint of desalination and brine treatment is a barrier to a green economy. Interfacial evaporation (IE) offers a sustainable approach to water purification by efficient energy conversion. However, conventional evaporators are susceptible to fluctuations in solar radiation and the salinity of handling liquid.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!