We present the synthesis and characterization of the first non-classical Cl(i) polyinterhalide [NMe][F(ClF)] as well as the homologous polychloride [NPrMe][Cl]. Both salts were obtained from the reaction of the corresponding ammonium chlorides with ClF or Cl, respectively. Quantum-chemical investigations predict an unexpected planar structure for the [F(ClF)] anion.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8117328 | PMC |
| http://dx.doi.org/10.1039/d1cc01088c | DOI Listing |
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Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)].
Chem Commun (Camb)
May 2021
Freie Universität Berlin, Department for Chemistry and Biochemistry, Fabeckstr. 34/36, Berlin, Germany.
We present the synthesis and characterization of the first non-classical Cl(i) polyinterhalide [NMe][F(ClF)] as well as the homologous polychloride [NPrMe][Cl]. Both salts were obtained from the reaction of the corresponding ammonium chlorides with ClF or Cl, respectively. Quantum-chemical investigations predict an unexpected planar structure for the [F(ClF)] anion.
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