Covalent organic frameworks (COFs) have attracted extensive attention due to their low density, adjustable structure, functionalization, and good stability. This paper systematically and comprehensively describes to qualitatively and quantitatively the progress, trends, and hotspots of COFs in the environmental and energy fields from the perspective of bibliometrics. Herein, based on the Web of Science database, a total of 2589 articles from 2005 to October 6, 2020, were collected. Thereafter, co-occurrence, co-citation analysis, and cluster analysis were conducted using CiteSpace and VOSviewer software. The results indicated that COFs research shows the characteristics of rapid growth. The active countries were mainly USA, Germany, Japan, China, and India. More than half of the top 20 active institutions were from China. The research hotspots in this field were systematically elaborated, including synthesis, adsorption, catalysis, membrane, sensor, and energy storage. Research has shown that various COFs are reasonably designed, synthesized, and used in different applications. For example, when COFs are used for photocatalysis, groups containing photocatalytic active sites are integrated into COFs to improve photocatalytic activity. Finally, some challenges were proposed, that are beneficial to the rapid and balanced development of the COFs field. For instance, the preparation methods still need to be further improved for mass production and there is an imbalance in environmental applications such as fewer sensor and membrane applications. We believe that this study provides a comprehensive and systematic overview of the environmental and energy applications of COFs for future investigations.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1016/j.scitotenv.2021.146838 | DOI Listing |
Environ Toxicol Chem
January 2025
Savannah River Ecology Lab, University of Georgia, Aiken, SC, USA.
Legacy contaminants tied to energy production are a worldwide concern. Coal combustion residues (CCRs) contain high concentrations of potentially toxic trace elements such as arsenic (As), mercury (Hg), and selenium (Se), which can persist for decades after initial contamination. CCR disposal methods, including aquatic settling basins and landfills, can facilitate environmental exposure through intentional and accidental releases.
View Article and Find Full Text PDFLangmuir
January 2025
School of Environment and Energy, South China University of Technology, Guangzhou 510006, People's Republic of China.
The anionic species of antimony(V) and phosphate(V) are commonly found in the contaminated soil of mining areas, exerting a significant influence on the sorption of heavy metals and thus affecting their migration. This study quantitatively discussed the sorption mechanism of Sb and P in promoting the sorption of Cd or Cu on goethite through a series of extraction methods. In the single sorption system, the majority of Cu (87-98%) is adsorbed on goethite in the form of EDTA-extractable Cu (EF Cu, possibly inner-sphere complexes) under pH conditions of 3.
View Article and Find Full Text PDFBiodegradation
January 2025
Master's Program of Green Energy Science and Technology, Feng Chia University, Taichung City, 407102, Taiwan.
Bioplastics, particularly polyhydroxyalkanoates (PHAs), are emerging as promising alternatives to traditional materials due to their biodegradability. This study focuses on the production of PHAs as bioplastics using effluent from hydrogen production in a two-stage Biohythane Pilot Plant, which provides a low-cost substrate. The aim is to optimize production conditions, with Cupriavidus necator TISTR 1335 being used as the PHA producer.
View Article and Find Full Text PDFAppl Microbiol Biotechnol
January 2025
Department of Chemical Engineering, University of California, Santa Barbara, CA, 93106, USA.
The animal gut microbiome is a complex system of diverse, predominantly anaerobic microbiota with secondary metabolite potential. These metabolites likely play roles in shaping microbial community membership and influencing animal host health. As such, novel secondary metabolites from gut microbes hold significant biotechnological and therapeutic interest.
View Article and Find Full Text PDFNanoscale
January 2025
Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, Pennsylvania 15261, USA.
Single atom alloys (SAAs) have gained tremendous attention as promising materials with unique physicochemical properties, particularly in catalysis. The stability of SAAs relies on the formation of a single active dopant on the surface of a metal host, quantified by the surface segregation and aggregation energy. Previous studies have investigated the surface segregation of non-ligated and ligated SAAs to reveal the driving forces underlying such phenomena.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!