Blue/yellow emissive carbon dots coupled with curcumin: a hybrid sensor toward fluorescence turn-on detection of fluoride ion.

Trace detection of fluoride ion has gained increasing attention due to fluoride's close association with biological and environmental processes. Herein, we construct a novel hybrid nanosystem consisting of carbon dots and curcumin for sensitive and selective sensing of F. Carbon dots are synthesized by hydrothermal treatment of 2,3-diaminopyridine and selenourea in hydrochloric acid. This material is employed as the fluorescent indicator that exhibits intense blue and yellow emission with quantum yields of 12% and 33%, respectively. Curcumin, possessing an absorption peak at 532 nm, can significantly quench the yellow fluorescence of carbon dots through inner filter effect. Curcumin is also used to specifically recognize F. When F is added, the curcumin-F complex generates, which leads to the hypochromatic shift of the absorption band from 532 to 430 nm. In such a case, the inner filter effect reduces, and yellow fluorescence of carbon dots recovers. Thus, a fluorescence turn-on sensor of F is built based on the carbon dots/curcumin system. The limits of detection and quantitation are measured to be 0.39 and 1.30 μM, respectively. For real usage, the proposed method is applied to determinate F in tap water and milk samples with relative standard deviations below 7.9%.