Sandpaper wastes were used as adsorbent after pyrolysis at 500 °C and calcination at 800 °C for the removal of brilliant green and malachite green cationic dye from an aqueous solution. The effects of the pH, the adsorbent dose, the contact time, and the initial dye concentration on the removal efficiencies were investigated. The isotherm studies were conducted by using the Langmuir, Freundlich, and Dubinin-Radushkevich models, and thermodynamic studies were also performed. The adsorption of the Brilliant green and malachite green were found to comply with the Langmuir isotherm model and the Freundlich isotherm model, respectively. The thermodynamic studies showed that the adsorption of dyes were endothermic. The E values obtained from the Dubinin-Radushkevich isotherm showed that the adsorption mechanism was chemical in nature. Furthermore, the three kinetic models (pseudo first-order, pseudo second-order, and intraparticle diffusion) were investigated. It was found that the pseudo second-order kinetic model fitted well for adsorption of dyes.
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Nanoscale
January 2025
Department of Chemistry, Faculty of Science, Umm Al-Qura University, 21955 Makkah, Saudi Arabia.
With the growing threat of organic pollutants in water bodies, there is an urgent need for sustainable and efficient water decontamination methods. This research focused on synthesizing a novel Z-scheme ternary heterostructure composed of graphene oxide (GO)-mediated polyaniline (PANI) with α-FeO and investigated its potential in brilliant green (BrG) and ciprofloxacin (CIP) degradation tests under visible light. The ternary composite demonstrated exceptional photocatalytic activity, with the optimized 10%PANI/GO/α-FeO (10PGF) photocatalyst achieving 99.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
School of Chemical Engineering, Universiti Sains Malaysia, Engineering Campus, 14300 Nibong Tebal, Penang, Malaysia.
Environ Sci Pollut Res Int
January 2025
Department of Chemistry, National Institute of Technology, Silchar, 788010, Assam, India.
In this work, Terminalia chebula leaf extract was used to synthesize CuO-CoO nanoparticles, which were then embedded in a rice straw biochar. This new biochar-based nano-catalyst is used to photocatalytically degrade a variety of dyes (Eosin Y, Trypan Blue, Crystal Violet, Methylene Blue, Brilliant Green), as well as a binary mixture of Eosin Y and Trypan Blue dyes. It is also used for the catalytic reduction of nitro compounds (4-NP, 3-NP, and Picric acid).
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
PG and Research Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore 641 020, Tamil Nadu, India. Electronic address:
Smart polymer hydrogels with superior dye adsorption (brilliant green) characteristics were synthesized via free-radical polymerization by grafting acrylic acid segments onto allylated chitosan and inducing crosslinking with a trimethylolpropane triacrylate crosslinker. The synthesized adsorbents were characterized for their chemical structure (FT-IR and H NMR), thermal stability (TG/DTG), and morphological features (SEM). The adsorption capacity for brilliant green (934 mg/g) and water uptake (712 g/g) were determined using spectrophotometric and gravimetric methods, respectively.
View Article and Find Full Text PDFMolecules
November 2024
Dr. Ikram ul Haq Institute of Industrial Biotechnology, GC University, Lahore 54600, Pakistan.
The aim of the present research was the efficient degradation of industrial textile wastewater dyes using a very active cloned laccase enzyme. For this purpose, potent laccase-producing bacteria were isolated from soil samples collected from wastewater-replenished textile sites in Punjab, Pakistan. The laccase gene from locally isolated strain LI-81, identified as , was cloned into vector pET21a, which was further transformed into BL21 codon plus.
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