AI Article Synopsis
- Both multilayered (ML) and few-layered (FL) TiCT nanosheets were created using an etching and delaminating method, revealing different terminal groups.
- Characterization showed that ML-TiCT has O-related groups while FL-TiCT has hydroxyl groups, affecting their physical and chemical properties.
- ML-TiCT exhibits stronger near-field enhancements, but when coupled with Ag nanoparticles, the FL-TiCT structure allows for better confinement of the near-field due to electron injection from hydroxyl terminations.
Article Abstract
Both multilayered (ML) and few-layered (FL) TiCT nanosheets have been prepared through a typical etching and delaminating procedure. Various characterizations confirm that the dominant terminal groups on ML-TiCT and FL-TiCT are different, which have been assigned to O-related and hydroxyl groups, respectively. Such deviation of the dominant terminals results in the different physical and chemical performance and eventually makes the nanosheets have different potential applications. In particular, before coupling to Ag nanoparticles, ML-TiCT can present stronger near-field enhancement effect; however, Ag/FL-TiCT hybrid structure can confine stronger near-field due to the electron injection, which can be offered by the terminated hydroxyl groups.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8041988 | PMC |
| http://dx.doi.org/10.1186/s11671-021-03510-5 | DOI Listing |
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