Corrosion is a phenomenon that devastatingly affects innovative, industrial, and mechanical applications, especially in the oil and gas industries. The corrosion conceivably influences industrial equipment; it deteriorates the environment and lessens the equipment/infrastructure's lifetime. Considering the significant impact of corrosion in our daily lives, this review article aims to briefly discuss the significance of corrosion and different control methods with special attention on corrosion inhibitors. The classification of corrosion inhibitors based on types and their advantage/limitations, and heterocyclic compounds as potential corrosion inhibitors, mainly nitrogen-based compounds (pyridine (1N), pyrimidine (2N), and triazines (3N) fused ring benzimidazole, etc.), and their biological significance has been discussed in detail. The mechanism, challenges, and applications of heterocyclic compounds as corrosion inhibitors in various industrial relevant corrosive environments such as acid pickling, descaling operation in the desalination plant, oil gas industry, etc., have also been highlighted in the review.
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http://dx.doi.org/10.1002/asia.202100201 | DOI Listing |
Materials (Basel)
January 2025
Laboratorio de Física del Plasma, Universidad Nacional de Colombia Sede Manizales, Campus la Nubia, Km 9 via al Magdalena, Manizales 170007, Colombia.
In this study, we research the innovative application of multi-walled carbon nanotubes (MWCNTs) as corrosion inhibitors in Portland cement embedded steel. The physicochemical properties of the dispersion solutions were evaluated, varying the storage time, to analyze their effect on corrosion resistance. Using a dispersion energy of 440 J/g and a constant molarity of 10 mM, stable dispersions were achieved for up to 3 weeks.
View Article and Find Full Text PDFCarbohydr Polym
March 2025
School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, China; Institute of Advanced Materials, China University of Petroleum (East China), Qingdao 266580, China.
Research on stimuli-responsive micro-nanocontainers has gained attention for targeted corrosion inhibition and controlled emulsification-demulsification in oil recovery. However, existing nanocontainers face issues like irreversible drug release and limited functionality. This study presents a multi-functional nanocontainer design with reversible drug release and emulsification-demulsification capabilities.
View Article and Find Full Text PDFJ Fluoresc
January 2025
Scientific and Educational and Innovation Center for Chemical and Pharmaceutical Technologies, Ural Federal University named after the First President of Russia B.N. Yeltsin, Ekaterinburg, 620002, Russian Federation.
Since corrosion causes significant harm to the environment and economy, sustainable corrosion inhibitors are essential. This study set out to examine Anti-corrosion ability of a number of closely related polycyclic compounds of flavone derivatives, namely 5,7-dimethoxyflavone (1), 4',5,7-trimethoxyflavone (2), 3',4',5'-trimethoxyflavone (3), 5-hydroxy-3,3',4',7-tetramethoxyflavone (4), tangeretin (5), 3,3',4',5,6,7,8-heptamethoxyflavone (6), 3',5,7-trihydroxy-4',5',6-trimethoxyflavone (7) and 3',4',5,7-tetrahydroxy-3,6,8-trimethoxyflavone (8), using the DFT/B3LYP/6-311 + + G(d, p) basis set. Monte Carlo simulations were used to reveal the adsorption of the investigated compounds on the Cu(111) surface.
View Article and Find Full Text PDFAntibiotics (Basel)
December 2024
Department of Organic Chemistry, Biochemistry and Catalysis, Faculty of Chemistry, University of Bucharest, Soseaua Panduri, 030018 Bucharest, Romania.
The indole nucleus stands out as a pharmacophore, among other aromatic heterocyclic compounds with remarkable therapeutic properties, such as benzimidazole, pyridine, quinoline, benzothiazole, and others. Moreover, a series of recent studies refer to strategies for the synthesis of bisindole derivatives, with various medicinal properties, such as antimicrobial, antiviral, anticancer, anti-Alzheimer, anti-inflammatory, antioxidant, antidiabetic, etc. Also, a series of natural bisindole compounds are mentioned in the literature for their various biological properties and as a starting point in the synthesis of other related bisindoles.
View Article and Find Full Text PDFHeliyon
December 2024
Department of Chemical Engineering, Madonna University, Akpugo Campus, 402105, Akpugo, Enugu State, Nigeria.
The present study examined the corrosion protection of aluminium in 1M HCl by deploying expired danacid, with techniques such as gravimetric, electrochemical, and density functional theory (DFT). Inhibitor characterization was executed with Fourier transform infrared (FTIR) spectroscopy and gas chromatography mass spectrometry (GC-MS), which was supplemented by optimization of parameters with response surface methodology. The results of gravimetric study indicates that the inhibition efficiency (IE) rose with rise in danacid concentration and reduced with rise in temperature.
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