We present a many-body theory of exciton-trion polaritons (ETPs) in doped two-dimensional semiconductor materials. ETPs are robust coherent hybrid excitations involving excitons, trions, and photons. In ETPs, the 2-body exciton states are coupled to the material ground state via exciton-photon interaction, and the 4-body trion states are coupled to the exciton states via Coulomb interaction. The trion states are not directly optically coupled to the material ground state. The energy-momentum dispersion of ETPs exhibit three bands. We calculate the energy band dispersions and the compositions of ETPs at different doping densities using Green's functions. The energy splittings between the polariton bands, as well as the spectral weights of the polariton bands, depend on the strength of the Coulomb coupling between the excitons and the trions, which in turn depends sensitively on the doping density. The doping density dependence of the ETP bands and the charged nature of the trion states could enable novel electrical and optical control of ETPs.
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http://dx.doi.org/10.1103/PhysRevLett.126.127402 | DOI Listing |
Adv Mater
December 2024
State Key Laboratory for Artificial Microstructure & Mesoscopic Physics and Frontiers Science Center for Nano-Optoelectronics, School of Physics, Peking University, Beijing, 100871, China.
Despite extensive studies on magnetic proximity effects, the fundamental excitonic properties of the 2D semiconductor-magnet heterostructures remain elusive. Here, the presence of localized excitons in MoSe/CrSBr heterostructures is unveiled, represented by a new photoluminescence emission feature, X. Our findings reveal that X originates from excitons confined by intrinsic defects in the CrSBr layer.
View Article and Find Full Text PDFACS Nano
December 2024
Technology Innovation Center of Materials and Devices for Extreme Environment, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China.
Defects in chemical vapor deposition (CVD)-grown monolayer MoS are unavoidable and provide a powerful approach to creating single-photon emitters and quantum information systems through localizing excitons. However, insight into the A trion and B/C exciton localization in monolayer MoS remains elusive. Here, we investigate defect-mediated A trion and B/C exciton localization and relaxation in CVD-grown monolayer MoS samples via transient absorption spectroscopy.
View Article and Find Full Text PDFNanophotonics
February 2024
Faculty of Physics, University of Warsaw, ul. Pasteura 5, 02-093 Warszawa, Poland.
We present femtosecond pump-probe measurements of neutral and charged exciton optical response in monolayer MoSe to resonant photoexcitation of a given exciton state in the presence of 2D electron gas. We show that creation of charged exciton (X) population in a given K, K valley requires the capture of available free carriers in the opposite valley and reduces the interaction of neutral exciton (X) with the electron Fermi sea. We also observe spectral broadening of the X transition line with the increasing X population caused by efficient scattering and excitation induced dephasing.
View Article and Find Full Text PDFNanophotonics
August 2024
Faculty of Physics, Lomonosov Moscow State University, Moscow 119991, Russia.
Monolayers of transition metal dichalcogenides (TMDCs) demonstrate plenty of unique properties due to the band structure. Symmetry breaking brings second-order susceptibility to meaningful values resulting in the enhancement of corresponding nonlinear effects. Cooling the TMDC films to cryogenic temperatures leads to the emergence of two distinct photoluminescence peaks caused by the exciton and trion formation.
View Article and Find Full Text PDFNanophotonics
December 2023
Guangdong Provincial Key Laboratory of Nanophotonic Functional Materials and Devices, School of Information and Optoelectronic Science and Engineering, South China Normal University, Guangzhou 510006, China.
Two-dimensional (2D) transition metal dichalcogenide (TMDC) monolayers are promising materials for light-emitting devices due to their excellent electric and optical properties. However, defects are inevitably introduced in the fabrication of TMDC monolayers, significantly influencing their emission properties. Although photoluminescence (PL) is considered as an effective tool for investigating the defects in TMDC monolayers.
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