Herein, we fabricated and investigated the carbon nanotube (CNT) integrated metamaterial for orthogonal polarization control in the THz regime, which is composed of a sandwiched CNT layer with the adjacent metal gratings in the sub-wavelength integration. Under the mechanism of multilayer polarization selection and multiple reflections in CNT constructed micro-cavity, the perfect orthogonal polarization conversion is achieved and the transmittance spectrum presents multi-band peaks and valleys, which coincide with the theoretical Fabry-Perot resonance. Besides, by controlling the layer number and orientations of the middle CNT, the active modulation of the amplitude and phase in compound metamaterials are realized. Based on the simulation of CNT in the grating model, it obtains a good agreement with the experimental results, and the simulated electric field distribution also confirmed the inner polarization conversion mechanism. This work combines nanomaterials with optical microstructures and successfully applies them to the THz polarization control, which will bring new ideas for design novel THz devices.
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http://dx.doi.org/10.1364/OE.421552 | DOI Listing |
Sci Adv
January 2025
National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou, Jiangsu 215123, China.
Flexible thermoelectric systems capable of converting human body heat or solar heat into sustainable electricity are crucial for the development of self-powered wearable electronics. However, challenges persist in maintaining a stable temperature gradient and enabling scalable fabrication for their commercialization. Herein, we present a facile approach involving the screen printing of large-scale carbon nanotube (CNT)-based thermoelectric arrays on conventional textile.
View Article and Find Full Text PDFSci Adv
January 2025
Department of Mechanical Engineering, University of Delaware, Newark, DE 19716, USA.
Enhancing transport and chemomechanical properties in cathode composites is crucial for the performance of solid-state batteries. Our study introduces the filler-aligned structured thick (FAST) electrode, which notably improves mechanical strength and ionic/electronic conductivity in solid composite cathodes. The FAST electrode incorporates vertically aligned nanoconducting carbon nanotubes within an ion-conducting polymer electrolyte, creating a low-tortuosity electron/ion transport path while strengthening the electrode's structure.
View Article and Find Full Text PDFACS Nano
January 2025
Graduate Institute of Ferrous & Eco Materials Technology (GIFT), Pohang University of Science and Technology University, Pohang 37666, Republic of Korea.
Lattice volume changes in Li-ion batteries active materials are unavoidable during electrochemical cycling, posing significant engineering challenges from the particle to the electrode level. In this study, we present an elastic framework coating designed to absorb and reversibly release strain energy associated with particle volume changes, thereby enhancing mechanical resilience at both the particle and electrode levels. This framework, composed of multiwalled carbon nanotubes (MWCNTs), is applied to nickel-rich LiNiCoMnO (NCM9055) cathodes at a low loading of 0.
View Article and Find Full Text PDFFront Chem
December 2024
Circa Renewable Chemistry Institute, Department of Chemistry, University of York, York, United Kingdom.
This study focuses on the fabrication and characterisation of single-walled carbon nanotube (SWCNT) buckypapers and polyethersulfone (PES) flat-sheet membranes using Cyrene, aiming toevaluate its efficacy as a green solvent for these applications. Pristine SWCNTs were dispersed inCyrene without surfactants and compared to N-Methyl-2-pyrrolidone (NMP) dispersions. Buckypapers were fabricated from these dispersions and characterised using Scanning ElectronMicroscopy (SEM), Atomic Force Microscopy (AFM), and infrared spectroscopy.
View Article and Find Full Text PDFNanoscale
January 2025
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, P. R. China.
The rational design of advanced oxygen reduction reaction (ORR) catalysts is essential to improve the performance of energy conversion devices. However, it remains a huge challenge to construct hierarchical micro-/meso-/macroporous nanostructures, especially mesoporous transport channels in catalysts, to enhance catalytic capability. Herein, motivated by the characteristics of energetic metal-organic frameworks (EMOFs) that produce an abundance of gases during high-temperature pyrolysis, we prepared a unique tetrazine-based EMOF-derived electrocatalyst (denoted as FeC@NSC-900) consisting of highly dispersed FeC nanoparticles and N,S-codoped mesoporous carbon nanotubes.
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