Herein, we have theoretically investigated the sensing performance-including enormous increase in the sensitivity and figure of merit (FOM)-of a magneto-optical surface plasmon resonance (MOSPR) sensor, which is based on the transverse magneto-optical Kerr effect (T-MOKE) in a ferromagnet coupled with a noble-metal grating. Specifically, we propose to use a CoFeB magnetic slab covered by a subwavelength, periodic gold grating configured as a magnetoplasmonic heterostructure. In such a device, sharp, Fano-like T-MOKE signals of high amplitude can be achieved due to the surface plasmon resonances (SPRs) excited in the presence of the gold grating, especially after optimizing the grating period. Tiny changes in the refractive index of an analyte surrounding the MOSPR sensor can be measured by analyzing the shift in the angle of incidence of the resonance positions of the T-MOKE signals. By calculating these resonance positions, we have demonstrated that it is possible to achieve a considerable sensitivity of 105° RIU and a FOM as high as ∼10. Such a MOSPR sensing system can be exploited in biosensors with high detection limits.
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http://dx.doi.org/10.1364/OE.414749 | DOI Listing |
Chem Asian J
January 2025
Universidad Austral de Chile, Instituto de Ciencias Químicas, CHILE.
Plasmonic materials can be utilized as effective platforms to enhance luminescent signals of luminescent metal nanoclusters (LMNCs). Both surface enhanced fluorescence (SEF) and shell-isolated nanoparticle-enhanced fluorescence (SHINEF) strategies take advantage of the localized and increased external electric field created around the plasmonic metal surface when excited at or near their characteristic plasmonic resonance. In this context, we present an experimental and computational study of different plasmonic composites, (Ag) Ag@SiO2 and (Au) Au@SiO2 nanoparticles, which were used to enhance the luminescent signal of Au nanoclusters coated with glutathione (GSH) molecule (Au25GSH NCs).
View Article and Find Full Text PDFSensors (Basel)
December 2024
Institute of Fundamental Technological Research, Polish Academy of Sciences, ul. Pawińskiego 5B, 02-106 Warsaw, Poland.
In this paper, we demonstrate that torsional surface elastic waves can propagate along the curved surface of a metamaterial elastic rod (cylinder) embedded in a conventional elastic medium. The crucial parameter of the metamaterial rod is its elastic compliance s44(1)ω, which varies as a function of frequency ω analogously to the dielectric function εω in Drude's model of metals. As a consequence, the elastic compliance s44(1)ω can take negative values s44(1)ω<0 as a function of frequency ω.
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December 2024
Center for Experimental Chemistry Education of Shandong University, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China.
In this study, a simple and easy synthesis strategy to realize the modification of AuHgPt nanoalloy materials on the surface of ITO glass at room temperature is presented. Gold nanoparticles as templates were obtained by electrochemical deposition, mercury was introduced as an intermediate to form an amalgam, and then a galvanic replacement reaction was utilized to successfully prepare gold-mercury-platinum (AuHgPt) nanoalloys. The obtained alloys were characterized by scanning electron microscopy, UV-Vis spectroscopy, X-ray photoelectron spectroscopy and X-ray diffraction techniques.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Hainan Engineering Research Center of Tropical Ocean Advanced Opto-Electrical Functional Materials, College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China.
Chrysoidin (CG) can be ingested into the human body through the skin and cause chronic toxicity, so the detection of CG levels in the environment is crucial. In this study, we synthesize F-Ag@ZIF-8/PVC molecular-imprinted membranes (FZAP-MIM) by an innovative combination of SERS detection, membrane separation, and a molecular-imprinted technique in order to perform the analysis of CG in water. The plasmonic MOF material as a SERS substrate helps to enrich the target and realize the spatial overlap of the target with the nanoparticle tip "hotspot".
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January 2025
Yunnan Provincial Key Laboratory of Energy Saving in Phosphorus Chemical Engineering and New Phosphorus Materials, Yunnan International Joint Laboratory of Sustainable Polymers, The Higher Educational Key Laboratory for Phosphorus Chemical Engineering of Yunnan Province, Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China.
The growing demand for sustainable energy storage solutions has underscored the importance of phase change materials (PCMs) for thermal energy management. However, traditional PCMs are always inherently constrained by issues such as leakage, poor thermal conductivity, and lack of solar energy conversion capacity. Herein, a multifunctional composite phase change material (CPCM) is developed using a balsa-derived morphology genetic scaffold, engineered via bionic catechol surface chemistry.
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