Nonspherical liquid metal microparticles (NLMs) show extraordinary potential in various applications due to their multifunctional and structural advantages. To one-step-produce shaped NLMs with high efficiency, high controllability, and free of template, a facile microfluidic strategy named rotary flow shearing (RFS) is reported. A high-speed viscous shearing flow is provided by two counter-rotating rotors in the carrier fluid, inducing continuous pinch-off of liquid metal flowing from a capillary tube positioned in face of the slit between two rotors. The real-time oxidation realizes the rapid solidification of the pinching neck and the liquid metal surface during the RFS process, resulting in massive NLMs. Different from other microfluidic methods, the RFS enables tunable shapes of NLMs, especially for working materials at high viscosities. The collected NLMs exhibit special electrostatic-responsive performances including translation, rotation, reciprocation, and lining up under the manipulation of an external electric field. Such NLMs can be promisingly used for the construction of novel micromotors and soft electronics.
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http://dx.doi.org/10.1021/acsami.1c01026 | DOI Listing |
J Environ Manage
January 2025
Faculty of Geology, Geophysics and Environmental Protection, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059, Krakow city, Poland.
Fly ash, produced during coal combustion for energy making, which is recognized as an industrial by-product, could lead to environmental health hazards. Subsequently, fly ash found that an exceptional adsorption performance for the removal of various toxic pollutants, the adsorption capacity of fly ash might be altered by introducing physical/chemical stimulation. Successfully converting fly ash into zeolites not only recovers their disposal difficulties but also transforms unwanted materials into merchandisable products for various industrial applications.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
Engineering Laboratory for AgroBiomass Recycling & Valorizing, College of Engineering, China Agricultural University, Beijing 100083, China. Electronic address:
Plastic mulching film is ubiquitous in modern agriculture for its heat preservation and moisture retention functions. However, plastic mulching film waste accumulated on land results in microplastic pollution, posing potential hazards as these micro and nanoplastics can enter the food chain. Chemical upcycling of waste mulching film is an emerging strategy to realize sustainable development and circular economy.
View Article and Find Full Text PDFLangmuir
January 2025
College of Chemistry and Chemical Engineering, Qingdao University, Qingdao 266071, China.
The recovery of valuable materials from spent lithium-ion batteries (LIBs) has experienced increasing demand in recent years. Current recycling technologies are typically energy-intensive and are often plagued by high operation costs, low processing efficiency, and environmental pollution concerns. In this study, an efficient and environmentally friendly dielectrophoresis (DEP)-based approach is proposed to separate the main components of "black mass" mixtures from LIBs, specifically lithium iron phosphate (LFP) and graphite, based on their polarizability differences.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Centre for Robotics and Automation, Department of Biomedical Engineering, City University of Hong Kong, Hong Kong 999077, China.
Liquid metals are highly conductive like metallic materials and have excellent deformability due to their liquid state, making them rather promising for flexible and stretchable wearable sensors. However, patterning liquid metals on soft substrates has been a challenge due to high surface tension. In this paper, a new method is proposed to overcome the difficulties in fabricating liquid-state strain sensors.
View Article and Find Full Text PDFNatl Sci Rev
January 2025
State Key Laboratory of Physical Chemistry of Solid Surfaces, School of Electronic Science and Engineering, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Heterogeneous catalysts for parahydrogen-induced polarization (HET-PHIP) would be useful for producing highly sensitive contrasting agents for magnetic resonance imaging (MRI) in the liquid phase, as they can be removed by simple filtration. Although homogeneous hydrogenation catalysts are highly efficient for PHIP, their sensitivity decreases when anchored on porous supports due to slow substrate diffusion to the active sites and rapid depolarization within the channels. To address this challenge, we explored 2D metal-organic layers (MOLs) as supports for active Rh complexes with diverse phosphine ligands and tunable hydrogenation activities, taking advantage of the accessible active sites and chemical adaptability of the MOLs.
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