This work presents the results of phase transformation kinetics during continuous cooling in newly developed high strength low-alloy steel (HSLA). Initial theoretical calculations for the determination of heat treatment parameters were conducted. To determine the structural constituents formed due to the austenite decomposition the dilatometry approach was used. The material was cooled down from the austenitization temperature of 1000 °C with cooling rates between 0.1 °C/s to 60 °C/s. Then, light and scanning electron microscopy investigations were carried out. The microstructure after cooling at rates between 0.1 °C/s up to 1 °C/s is mainly ferritic with some fraction of granular bainite. Increasing the cooling rate led to formation of a higher fraction of bainitic ferrite. At 60 °C/s the microstructure was mainly bainite with some fraction of ferrite. To determine the presence of retained austenite, color etching using Klemm solution was used. The results show that the increase of cooling rate decreases the amount of retained austenite in the microstructure of the steel. Hardness measurements were made to determine the changes in the mechanical properties as a function of the cooling rate.
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http://dx.doi.org/10.3390/ma14071698 | DOI Listing |
Inorg Chem
January 2025
Department of Applied Chemistry, Faculty of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan.
-site cation ordering in double perovskites is crucially important for their physical properties. In this study, polycrystalline samples of Zr-based double perovskite NaLaZrO were synthesized via high-temperature solid-state reactions, and the influence of the heating temperature and cooling rate on their crystal structures was investigated using synchrotron X-ray diffractometry and optical second harmonic generation. The samples prepared at 1200 °C, followed by slow cooling to room temperature, crystallize in a polar 2 structure, exhibiting partial -site cation ordering, with Na- and La-rich -site layers alternately stacked along the axis.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Grain Science and Industry, Kansas State University, Manhattan, KS 66506, USA. Electronic address:
Starch spherulite is a unique form of resistant starch characterized by a spherical structure with crystalline lamellae that are radially oriented and may find applications in delivery of nutrients and bioactives to the lower gastrointestinal tract. Formation of starch spherulites generally requires heating to a high temperature followed by quenching and long crystallization time. The objectives of this study were to gain a deeper understanding of the factors influencing spherulite formation from pea starch (PS) and high-amylose maize starch (HAMS) and investigate if spherulites could be formed by a slow cooling rate and determine the crystalline structure and morphology of the spherulites formed.
View Article and Find Full Text PDFFoods
December 2024
Department of Marine Bio Food Science, Gangneung-Wonju National University, 7 Jukheon-gil, Gangneung 25457, Gangwon-do, Republic of Korea.
Commercial ascorbyl-6-O-esters (AEs) are composed of saturated fatty acids with relatively high melting points, resulting in limited solubility in lipophilic media. Therefore, a lipase-catalysed synthesis and purification method for ascorbyl-6-O-oleate (AO) was proposed in this study. The esterification synthesis (i.
View Article and Find Full Text PDFNanotechnology
January 2025
Universiti Teknologi PETRONAS, Centre of Innovative Nanostructures and Nanodevices (COINN), Universiti Teknologi PETRONAS, 32610 Seri Iskandar, Perak Darul Ridzuan, MALAYSIA, Seri Iskandar, Perak, 32610, MALAYSIA.
Most previously reported susceptors for microwave welding are in powder form. In this study, a thin-film susceptor was employed due to its uniform heating rate and ease of handling. Silicon carbide nanowhisker (SiCNW) were incorporated into a poly(methyl methacrylate) (PMMA) matrix to create a nanocomposite thin film, which served as the susceptor.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
Center for Membrane Separation and Water Science & Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
Heatable super hydrophobic polyurethane (PU) sponges (S-GNS/CNT/PVA@PU) containing three-dimensional (3D) carbon nano-networks (CNNs) coatings made from two-dimensional (2D) expanded graphite nano-sheets (GNS) bridged by one-dimensional (1D) carbon nano-tubes (CNT) were constructed using polyvinyl alcohol (PVA) as binder, in which light and/or electric energy could be rapidly converted into heat to reduce the viscosity of spilled heavy oils, resulting in greatly increased oil. Their heavy oil recovery rate could reach 792 kg/(m·h) under combined light and Joule heating of 1 sun and 5 V. Surface heat dissipating coefficient Ks, heat dissipating index n, and surface heat absorption capacity Cs were studied relating to sizes and shapes of surface heating fields under varied heating modes.
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