We propose an all-dielectric magneto-photonic crystal with a hybrid magneto-optical response that allows for the simultaneous measurements of the surface and bulk refractive index of the analyzed substance. The approach is based on two different spectral features of the magneto-optical response corresponding to the resonances in p- and s-polarizations of the incident light. Angular spectra of p-polarized light have a step-like behavior near the total internal reflection angle which position is sensitive to the bulk refractive index. S-polarized light excites the TE-polarized optical Tamm surface mode localized in a submicron region near the photonic crystal surface and is sensitive to the refractive index of the near-surface analyte. We propose to measure a hybrid magneto-optical intensity modulation of p-polarized light obtained by switching the magnetic field between the transverse and polar configurations. The transversal component of the external magnetic field is responsible for the magneto-optical resonance near total internal reflection conditions, and the polar component reveals the resonance of the Tamm surface mode. Therefore, both surface- and bulk-associated features are present in the magneto-optical spectra of the p-polarized light.
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http://dx.doi.org/10.3390/s21061984 | DOI Listing |
Langmuir
January 2025
Department of Chemical Engineering and Materials Research Institute, Pennsylvania State University, University Park, Pennsylvania 16802, United States.
The chemical reactivity of glass surfaces is often studied with elemental analysis techniques, and although such characterization methods provide insights on compositional changes from exposure to specific chemical conditions, molecule-specific chemical reactions are not determined unambiguously. This study demonstrates the use of reflection-absorption infrared spectroscopy (RAIRS) to detect molecular species on alkali-free boroaluminosilicate and alkali aluminosilicate glasses, using acetic acid vapor as a model reactant to probe reaction sites at the surface with or without pretreatment by aqueous solutions of varied pH. With the assistance of the theoretical calculation of spectral changes based on refractive indices of bulk materials, it was possible to identify the molecular species being removed and produced at the glass surface.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
Emerging Technologies Research Center, XPANCEO, Internet City, Emmay Tower, Dubai, United Arab Emirates.
Due to their high refractive index, record optical anisotropy and a set of excitonic transitions in visible range at a room temperature, transition metal dichalcogenides have gained much attention. Here, we adapted a femtosecond laser ablation for the synthesis of WSe nanoparticles (NPs) with diameters from 5 to 150 nm, which conserve the crystalline structure of the original bulk crystal. This method was chosen due to its inherently substrate-additive-free nature and a high output level.
View Article and Find Full Text PDFSci Rep
January 2025
ISQI, Faculty of Physics, Adam Mickiewicz University in Poznań, Poznań, Poland.
High-resolution Brillouin spectroscopy was employed to investigate the anisotropy in surface wave velocities within a bulk single crystal of SbTe, a well-known layered van der Waals material. By leveraging the bulk elastic constants derived from various simulation methods, we were able to theoretically calculate the distribution of surface acoustic phonon velocities on the cleavage plane of the material. Upon analyzing multiple simulation results, it became evident that the most significant discrepancies arose in the calculations of the elastic constant c, with values ranging from 48 to 98 GPa.
View Article and Find Full Text PDFFoods
December 2024
Department of Biomedical Photonic Imaging, Faculty of Science and Technology, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands.
The refractive index (RI) of human milk serum (also known as whey, milk soluble fraction or milk plasma) depends on the individual molecular species dissolved in the serum and their concentrations. Although the human milk serum RI is known to influence milk analysis methods based on light scattering, the RI dependency on human milk serum composition is currently unknown. Therefore, we systematically evaluate how the RI depends on natural variations in macronutrient concentrations in the soluble fraction.
View Article and Find Full Text PDFCurr Res Food Sci
December 2024
Department of Chemical and Geological Sciences, University of Modena and Reggio Emilia, via G. Campi, 103, 41125 Modena, Italy.
Stable isotope analysis has become a valuable tool for studying food chain processes and verifying the authenticity and geographical origin of typical products. The analysis is particularly important for those foods with geographical indications, such as Aceto Balsamico Tradizionale di Modena labelled with the protected designation of origin mark (ABTM PDO) and Aceto Balsamico di Modena with the protected geographical indication (ABM PGI). Understanding how the aging process affects the isotopic composition of specific compounds in ABTM is important for distinguishing between traditional and non-traditional products, as well as for verifying their authenticity.
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