Photocatalysis is an effective and environmentally friendly approach for degrading organic pollutants, particularly in scenarios where sunlight can be utilized as the energy source. Opportunities are emerging to apply materials and methods from photocatalytic pollutant degradation to address the challenge of fouling. Membrane fouling, attributed to organic foulants, is a prevalent problem for all membrane-based technologies and represents a major deleterious impact on membrane performance. Integration of tactics developed in photocatalysis more broadly to membranes reveals new strategies for membrane fouling control-an approach taken by an increasing number of researchers. This review summarizes key developments in photocatalytic materials and methods in water treatment and presents recent progress in the development of processes for photocatalytic alleviation of membrane fouling, including photocatalyst design and modification strategies aimed at enhancing photocatalytic efficiency, as well as different configurations of photocatalysis-membrane systems (PMS). Perspectives on future research and development opportunities for photocatalytic membrane fouling control are also provided.
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http://dx.doi.org/10.1021/acsami.1c01131 | DOI Listing |
Chemosphere
March 2025
Ralph E. Martin Department of Chemical Engineering, University of Arkansas, Fayetteville, AR, 72701, United States. Electronic address:
This study aims to develop fouling-resistant membranes utilizing zwitterionic polymers for an integrated electrocoagulation (EC) and nanofiltration (NF) process to effectively remove microcystin-LR (MC-LR). The fabricated membranes were thoroughly characterized through contact angle measurements, Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The efficacy of these modified membranes was investigated for synthetic microcystin removal, employing both commercial NF 270 membranes and modified NF 270 with zwitterionic polymers.
View Article and Find Full Text PDFWater Res
February 2025
Guangdong-Hong Kong Joint Laboratory for Water Security, Beijing Normal University, Zhuhai 519087, China; Department of Civil and Environmental Engineering, National University of Singapore, 1 Engineering Drive 2, 117576, Singapore. Electronic address:
Aerobic granular sludge (AGS) has demonstrated a lower fouling propensity than floc sludge in membrane bioreactors (MBRs) due to various hypotheses, including differences in particle size and the efficacy of physical scouring. However, controversy exists regarding the dominant cause of this lower fouling. Therefore, in this work, we systematically investigated the contribution of four potential mechanisms of AGS on membrane fouling alleviation in MBRs: 1) loosening cake layer; 2) scouring of the membrane surface; 3) regulating soluble microbial product (SMP) secretion; and 4) changing the rheology of the bulk solution.
View Article and Find Full Text PDFEnviron Sci Technol
March 2025
Shandong Key Laboratory of Water Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Shandong University, Qingdao, Shandong 266237, P. R. China.
Loose nanofiltration (LNF) membranes with high permeance and separation selectivity are highly desired for the effective separation of organic dyes and inorganic salts. Herein, a novel polyamide LNF membrane was fabricated using zwitterionic amine reactant trimethylamine -oxide-based polyethylenimine (TPEI) and trimesoyl chloride (TMC) via interfacial polymerization (IP). A thin, loose, and smooth polyamide layer was formed due to the low diffusion rate and modified chemical structure of TPEI.
View Article and Find Full Text PDFSci Rep
March 2025
Faculty of Mechanical Engineering, University of Imam Khomeini Marine Sciences, Nowshahr, Iran.
This study introduces a novel application of electrocoagulation (EC) as a pretreatment method for seawater desalination, uniquely focusing on reducing organic and biological fouling in reverse osmosis membranes. The EC process was investigated as an alternative to conventional approaches such as chemical coagulation, chlorination, and fouling inhibitors. EC was conducted in a batch cell using iron electrodes.
View Article and Find Full Text PDFACS Omega
March 2025
Chemistry School, Federal University of Rio de Janeiro, Av. Athos da Silveira Ramos 149, Rio de Janeiro, Rio de Janeiro 21941-909, Brazil.
Oil production entails the generation of large volumes of complex effluents that contain emulsified oil in water. Difficult to manage, the use of membrane separation processes (MSP) is an interesting option for the treatment of oily effluents, separating oil-in-water (o/w) emulsions with high efficiency. Modifying the surface of membranes with metals minimizes fouling, which is the main drawback of MSP.
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