The two novel organic hybrid iodoplumbates [Hhbpt][Hhbpt][Hhbpt][PbI]·9HO (, hbpt = 1-3,5- bis(pyrazinyl)-1,2,4-triazole) and [PbI(bpt)(HO)(I·1/2I)] () were synthesized under hydrothermal conditions. contains a new type of pentanuclear cluster [PbI] anion, while comprises an unprecedented 2-D polyiodoplumbate layer. Both and are potential semiconductors with narrow absorption edges of 1.98 eV for and 1.38 eV for . also shows photocurrent response and photoluminescent properties.
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| http://dx.doi.org/10.1021/acs.inorgchem.1c00330 | DOI Listing |
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