The ternary van der Waals material NbSiTe demonstrates many interesting properties as the content of Si is changed, ranging from metallic NbSiTe ( = 5/3) to narrow-gap semiconductor NbSiTe ( = 2) and with the emergence of one-dimensional Dirac fermion excitations in between. An in-depth understanding of their properties with different stoichiometry is important. Here we use scanning tunneling microscopy and spectroscopy to reveal that NbSiTe is a system with spontaneously developed and self-aligned one-dimensional metallic chains embedded in a two-dimensional semiconductor. Electron quasiparticles form one- and two-dimensional standing waves side by side. This special microscopic structure results in strong transport anisotropy. Along the chain direction the material behaves like a metal, while perpendicular to the chain direction, it behaves like a semiconductor. These findings provide an important basis for further investigation of this intriguing system.

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http://dx.doi.org/10.1021/acsnano.1c00320DOI Listing

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