Iodinated contrast media (ICM) are drugs which are used in medical examinations for organ imaging purposes. Wastewater treatment plants (WWTPs) have shown incapability to remove ICM, and as a consequence, ICM and their transformation products (TPs) have been detected in environmental waters. ICM show limited biotransformation and low sorption potential. ICM can act as iodine source and can react with commonly used disinfectants such as chlorine in presence of organic matter to yield iodinated disinfection byproducts (IDBPs) which are more cytotoxic and genotoxic than conventionally known disinfection byproducts (DBPs). Even highly efficient advanced treatment systems have failed to completely mineralize ICM, and TPs that are more toxic than parent ICM are produced. This raises issues regarding the efficacy of existing treatment technologies and serious concern over disinfection of ICM containing waters. Realizing this, the current review aims to capture the attention of scientific community on areas of less focus. The review features in depth knowledge regarding complete environmental fate of ICM along with their existing treatment options.
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http://dx.doi.org/10.1016/j.scitotenv.2020.144846 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Sun Yat-Sen University, Environmental Science and Engineering, CHINA.
Despite recent substantial advances in water treatment, the ability to selectively degrade trace micropollutants in real waters with complex matrix components remains a grand challenge. Here we report rational crafting of graphene oxide (GO)-wrapped defective TiO2 composite catalysts that creates nanoscopic confinement over the TiO2 surface within GO, thereby enabling the selective degradation of micropollutants through effectively excluding natural organic matter (NOM) and anions from the nanoconfined catalytic sites. In contrast to unconfined counterparts, the nanoconfined composite catalysts retain high degradation efficiency when exposed to various concentrations of NOM and anions, even in real water samples.
View Article and Find Full Text PDFSci Total Environ
January 2025
Key Laboratory for City Cluster Environmental Safety and Green Development of the Ministry of Education, Institute of Environmental and Ecological Engineering, Guangdong University of Technology, Guangzhou, 510006, China; Guangdong Basic Research Center of Excellence for Ecological Security and Green Development, Guangzhou, 510000, China.
OH-mediated advanced oxidation processes (AOPs) are widely used in wastewater treatment and drinking water purification. Recently, an increasing number of studies have indicated that common inorganic nitrogen ions can efficiently generate •OH under UV irradiation, demonstrating strong performance in the degradation of various contaminants. Conversely, the presence of inorganic nitrogen ions in UV or other oxidation processes dramatically increases the yield of toxic nitro (so)-aromatic products and the formation potential of nitrogenous disinfection by-products with high genotoxicity and cytotoxicity.
View Article and Find Full Text PDFSci Total Environ
January 2025
China National Environmental Monitoring Centre, Beijing 100012, China.
The riverine dissolved organic matter (DOM) pool constitutes the largest and most dynamic organic carbon reservoir within inland aquatic systems. Human activities significantly alter the distribution of organic matter (OM) in rivers, thereby affecting the availability of DOM. However, the impact of total suspended solids (TSS) on DOM under anthropogenic influence remains insufficiently elucidated.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Health Hazards Surveillance, Hangzhou Center for Disease Control and Prevention (Hangzhou Health Supervision Institution), Hangzhou, 310021, China.
Disinfection is a critical process to ensure the safety of drinking water. To curb the spread of various bacteria and viruses, disinfectants are extensively employed in communities, hospitals, sewage treatment plants, and other settings. However, disinfectants can produce disinfection by-products (DBPs) that threaten human health.
View Article and Find Full Text PDFSci Total Environ
January 2025
Laboratoire National d'Hydraulique et Environnement (LNHE), Division Recherche et Développement, Electricité de France (EDF), 6 Quai de Watier, 78401 Chatou Cedex 01, France.
This paper aims to test several modeling approaches for predicting toxicity of binary mixtures with potential synergy and antagonism. The approach based on the construction of isoboles was first tested and criticized. In contrast to conventional approaches, and in order to be mathematically consistent with the additivity assumptions, non-linear isoboles have been constructed.
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