The phase behavior and adsorption kinetics of hard-core particles on a honeycomb lattice are studied by means of random sequential adsorption with surface diffusion. We concentrate on reversible adsorption by introducing a desorption process into our previous model and varying the equilibrium rate constant as a control parameter. We find that an exact prediction of the temporal evolution of fractional surface coverage and the surface pressure dynamics of reversible adsorption can be achieved by use of the blocking function of a system with irreversible adsorption of highly mobile particles. For systems out of equilibrium we observe several features of glassy dynamics, such as slow relaxation dynamics, the memory effect, and aging. In particular, the analysis of our system in the limit of small desorption probability shows simple aging behavior with a power-law decay. A detailed discussion of Gibbs adsorption isotherm for nonequilibrium adsorption is given, which exhibits a hysteresis between this system and its equilibrium counterpart.

Download full-text PDF

Source
http://dx.doi.org/10.1103/PhysRevE.103.022801DOI Listing

Publication Analysis

Top Keywords

glassy dynamics
8
honeycomb lattice
8
surface diffusion
8
reversible adsorption
8
adsorption
7
surface
5
equilibrium
4
dynamics equilibrium
4
equilibrium state
4
state honeycomb
4

Similar Publications

Glassy Dynamics and Local Crystalline Order in Two-Dimensional Amorphous Silica.

J Phys Chem B

January 2025

Dipartimento di Fisica, Università di Trieste, Strada Costiera 11, 34151 Trieste, Italy.

We reassess the modeling of amorphous silica bilayers as a 2D classical system whose particles interact with an effective pairwise potential. We show that it is possible to reparametrize the potential developed by Roy, Heyde, and Heuer to quantitatively match the structural details of the experimental samples. We then study the glassy dynamics of the reparametrized model at low temperatures.

View Article and Find Full Text PDF

Microscopic structural origin of slow dynamics in glass-forming liquids.

Nat Mater

January 2025

Department of Fundamental Engineering, Institute of Industrial Science, The University of Tokyo, Tokyo, Japan.

Supercooled liquids display sluggish dynamics, often attributed to their structural characteristics, yet the underlying mechanism remains elusive. Here we conduct numerical investigations into the structure-dynamics relationship in model glass-forming liquids, with a specific focus on an elementary particle rearrangement mode known as the 'T1 process'. We discover that the ability of a T1 process to preserve glassy structural order before and after is pivotal towards determining a liquid's fragility-whether it exhibits super-Arrhenius-like or Arrhenius-like behaviour.

View Article and Find Full Text PDF

The paper starts by describing the manufacturing process of cups thermoformed from extruded foils of 80% recycled PET (80r-PET), which comprises heating, hot deep drawing and cooling. The 80r-PET foils were heated up to 120 °C, at heating rates of the order of hundreds °C/min, and deep drawn with multiple punchers, having a depth-to-width ratio exceeding 1:1. After puncher-assisted deformation, the cups were air blown away from the punchers, thus being "frozen" in the deformed state.

View Article and Find Full Text PDF

The challenge of increasing food production while maintaining environmental sustainability can be addressed by using biofertilizers such as Azospirillum, which can enhance plant growth and colonize more than 100 plant species. The success of this biotechnology depends on the amount of plant growth-promoting bacteria associated with the plant during crop development. However, monitoring bacterial population dynamics after inoculation requires time-consuming, laborious, and costly procedures.

View Article and Find Full Text PDF

We report the pressure-temperature (-) phase diagram, the origin of the subglass dynamics, and the crystallization kinetics of the biobased polyester poly(ethylene 2,5-furanoate) (PEF), through dielectric spectroscopy (DS) measurements performed as a function of temperature and pressure. The phase diagram comprises four different "phases"; glass, quenched melt, crystalline, and normal melt. The cold crystallization temperature, , increases linearly with pressure (according to the Clausius-Clapeyron equation) as / ∼ 240 K·GPa and is accompanied by a small change in specific volume (Δ = 0.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!