We generate optical fields whose polarization structures not only rotate about their propagation axis but also can be controlled to accelerate independently from their spatial profile. We show that by combining accelerated intensity transport with orthogonal polarization states, we can produce a vector beam that displays optical activity with periodical acceleration and deceleration of the Stokes vector during propagation. We achieve this with orthogonal, scalar fields, represented by weighted superpositions of oppositely charged Bessel beams. In addition to their creation, we show that the Stokes vector can be made to accelerate or decelerate at specific locations along the Poincaré sphere by tailoring the generating basis. We also witness an optical current, or intensity transport, between local positions in the field that corresponds with the occurrence of the state-of-polarization accelerating or decelerating.
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http://dx.doi.org/10.1364/OE.411029 | DOI Listing |
Acc Chem Res
January 2025
The Wolfson Catalysis Centre, Department of Chemistry, University of Oxford, Oxford OX1 3QR, U.K.
ConspectusThe discovery of reversible hydrogenation using metal-free phosphoborate species in 2006 marked the official advent of frustrated Lewis pair (FLP) chemistry. This breakthrough revolutionized homogeneous catalysis approaches and paved the way for innovative catalytic strategies. The unique reactivity of FLPs is attributed to the Lewis base (LB) and Lewis acid (LA) sites either in spatial separation or in equilibrium, which actively react with molecules.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
College of Physics, Liaoning University, Shenyang 110036, China.
Based on the DCV-C system of fullerene acceptor organic solar cell active materials, the charge transfer process of D-A type molecular materials under the action of an external electric field () was explored. Within the range of electric field application, the excited state characteristics exhibit certain regular changes. Based on reducing the excitation energy, the excitation mode shows a trend of developing toward low excited states.
View Article and Find Full Text PDFJ Opt Soc Am A Opt Image Sci Vis
August 2024
A fused-silica three-port grating under TE-polarized normal incidence is designed and manufactured with improved diffraction efficiency (DE) and bandwidth. A physical explanation of the grating diffraction is provided using the simplified mode method (SMM), and parameters of the grating structure were optimized using rigorous coupled-wave analysis (RCWA). For a given set of optimized parameters, a transmitted three-port grating with an area of 170 ×170 was fabricated by scanning beam interference lithography (SBIL), and diffraction properties were investigated.
View Article and Find Full Text PDFJ Opt Soc Am A Opt Image Sci Vis
August 2024
A criterion for the characterization of the retardance effects produced by depolarizing and nondepolarizing linear media on interacting light is established based on Mueller matrices algebra. A consistent general description of retardance properties is performed by means of a serial decomposition of the Mueller matrix into three components, namely an element that encompasses the enpolarizing and depolarizing properties sandwiched by two elliptical retarders containing complete and decoupled information on retardance. The inherent ambiguity derived from the coincident formal structure of rotation matrices and circular retarders is removed though the introduction of the entrance and exit intrinsic reference frames, leading to the concepts of the intrinsic entrance and exit linear retarders, which are defined from the Mueller matrix itself and that are independent of the laboratory reference frames used to represent the incident and emerging polarized light beams, respectively.
View Article and Find Full Text PDFSoft Matter
January 2025
Department of Physics, Kyoto University, Kyoto 606-8502, Japan.
This study explores the influence of charge distribution and molecular shape on the stability of ferroelectric nematic liquid crystalline phases through atomistic simulations of DIO molecules. We demonstrate the role of dipole-dipole interactions and molecular shape in achieving polar ordering by simulating charged and chargeless topologies, and analysing positional and orientational pair-distribution functions. The charged DIO molecules exhibit head-to-tail and side-by-side parallel alignments conducive to long-range polar order, whereas the chargeless molecules show no polar ordering.
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