Exchange bias in ferromagnetic/antiferromagnetic systems can be explained in terms of various interfacial phenomena. Among these, spin glass frustration can affect the magnetic properties in exchange bias systems. Here we have studied a NiMn/CoFeB exchange bias system in which spin glass frustration seems to play a crucial role. In order to account for the effect of spin glass frustration on magnetic properties, we have investigated the temperature and cooling field dependence of exchange bias. We have observed the decrease of exchange bias field (μH) with cooling field (μH) whereas there is a negligible effect on coercive field (μH). Exponential decay of μH and μH is found in this exchange bias system. Furthermore, training effect measurements have been performed to study the spin relaxation mechanism. We have fitted the training effect data with a frozen and rotatable spin relaxation model. We have determined the ratio of relaxation rates of interfacial rotatable and frozen spins in this study. The training effect data are also fitted with various other models. Furthermore, we have observed the shifting of the peak temperature towards higher temperature with frequency from the ac susceptibility data. The peak temperature vs. frequency data can be described by the Vogel-Fulcher law, which indicates the spin glass like state in the bilayer system.
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Angew Chem Int Ed Engl
January 2025
Humboldt-Universität zu Berlin, Department of Chemistry, Laboratory of Organic Chemistry and Functional Materials, Brook-Taylor-Str. 2, 12489, Berlin, GERMANY.
Here we disclose that spiropyrans are able to undergo dynamic covalent exchange via their corresponding merocyanine isomers. In the latter, the indolinium moieties can be exchanged by a Michael-type addition-elimination sequence, in which a methylene indoline attacks a merocyanine and subsequently the initial indoline fragment is cleaved. The rate and position of the exchange equilibrium strongly depend on the reaction conditions as well as the substitution pattern on the methylene indoline fragments.
View Article and Find Full Text PDFAdv Mater
January 2025
Center for Renewable Energy and Storage Technologies (CREST), Physical Science and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900, Kingdom of Saudi Arabia.
The sluggish anodic oxygen evolution reaction (OER) in proton exchange membrane (PEM) electrolysis necessitates applied bias to facilitate electron transfer as well as bond cleavage and formation. Traditional electrocatalysis focuses on analyzing the effects of electron transfer, while the role of charge accumulation induced by the applied overpotential has not been thoroughly investigated. To explore the influence mechanism of bias-driven charge accumulation, capacitive Mn is incorporated into IrO to regulate the local electronic structure and the adsorption behavior.
View Article and Find Full Text PDFHealth Care Sci
December 2024
School of Healthcare Management, Tsinghua Medicine Tsinghua University Beijing China.
The COVID-19 pandemic presented unparalleled challenges to prompt and adaptive responses from nations worldwide. This review examines China's multifaceted approach to the crisis, focusing on five key areas of response: infrastructure and system design, medical care and treatment, disease prevention and control, economic and social resilience, and China's engagement in global health. This review demonstrates the effectiveness of a top-down command system at the national level, intersectoral coordination, a legal framework, and public social governance.
View Article and Find Full Text PDFSci Rep
December 2024
Saha Institute of Nuclear Physics, A CI of Homi Bhabha National Institute, Kolkata, 700064, India.
Antiferromagnetic materials offer potential for spintronic applications due to their resilience to magnetic field perturbations and lack of stray fields. Achieving exchange bias in these materials is crucial for certain applications; however, discovering such materials remains challenging due to their compensated spin structure. The quest for antiferromagnetic materials with exchange bias became a reality through our experimental study and theoretical simulation on and .
View Article and Find Full Text PDFTransfus Apher Sci
December 2024
Alexion, AstraZeneca Rare Disease, 121 Seaport Blvd, Boston, MA 02210, USA. Electronic address:
Plasma exchange (PE) outcomes in patients with trigger-associated thrombotic microangiopathy (TMA) have not been comprehensively reviewed. Embase and MEDLINE® were searched on 03/14/2022 for English language articles published after 2007, alongside a congress materials search (2019-2022; PROSPERO: CRD42022325170). Studies with patients with trigger-associated TMA (excluding thrombotic thrombocytopenic purpura, 'typical' hemolytic uremic syndrome caused by Shiga toxin-producing Escherichia coli, post-partum TMA, and TMAs with known genetic cause) who received PE or plasma infusion (PI) and reported treatment response (including measures), safety, patient-/caregiver-reported outcomes, or economic burden data were examined.
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