CuO-based composites for photocatalysis have been extensively explored owing to their promising application in solving environmental and energy problems. At present, the research on photocatalysis is focused on improving the photocatalytic performance of materials. It has been reported that adjusting the morphology and size of CuO can effectively improve its photocatalytic property. However, photocorrosion is still an inevitable problem, which hinders the application of CuO in photocatalysis. The strategies of constructing heterogeneous nanostructures and ion doping can significantly improve the light stability, light absorption capacity and separation efficiency of electron-hole pairs. CuO-based composites exhibit superior performances in degrading organic matter, producing hydrogen, reducing CO and sterilization. Therefore, the construction of multi-materials will be one of the future directions in their photocatalytic application. This review summarizes the recent strategies for enhancing the photocatalytic activity of CuO by analyzing different CuO-based photocatalysts, and the charge transfer pathway is further discussed in detail. Finally, several opportunities and challenges in the field of photocatalysis are illustrated.
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http://dx.doi.org/10.1039/d0dt04434b | DOI Listing |
Inorg Chem
December 2024
Department of Chemistry, Sharif University of Technology, Tehran 11155-9516, Iran.
This study explores the influence of Fe ion incorporation on the oxygen-evolution reaction (OER) in alkaline media, utilizing CuO-based materials. Instead of developing an efficient and stable OER catalyst, this research investigates two distinct CuO variants: one with Fe ions adhered to the surface and another with Fe ions integrated into the CuO lattice. By employing a variety of analytical techniques, the study demonstrates that the CuO variant with surface-bound Fe ions (referred to as compound 1) exhibits significantly enhanced OER performance compared to the variant with internally embedded Fe ions (referred to as compound 2).
View Article and Find Full Text PDFNanotechnology
August 2024
School of Integrated Science and Innovation, Sirindhorn International Institute of Technology Thammasat University, Rangsit, Bangkadi 12120, Thailand.
Metal organic frameworks (MOF's) have gained considerable attention in the field of energy storage and supercapacitors applications. Herein, we synthesized copper oxide (CuO) through the precipitation method and concurrently derived from the solvothermal prepared copper-benzene dicarboxylate (Cu-BDC) by calcination. The integration of MOF-derived nanostructures with traditional CuO to form a hybrid electrode material, has not been extensively explored.
View Article and Find Full Text PDFMaterials (Basel)
June 2024
School of Chemical Engineering, Yeungnam University, 280 Daehak-Ro, Gyeongsan 38541, Republic of Korea.
The present study reports on the preparation of a cellulose fiber (CF) composite from , combined with copper oxide nanoparticles (DL@CF/CuO), to prolong the shelf life of tomatoes after harvest. The isolated cellulose fiber material was comprehensively characterized using XRD, FTIR, and FE-SEM analyses. The DLCF and DL@CF/CuO nanoparticles exhibited crystalline cellulose, as indicated by the XRD investigation.
View Article and Find Full Text PDFACS Omega
August 2023
Smart Materials and Sensor Laboratory, Department of Physics, Chaudhary Charan Singh University, Meerut, Uttar Pradesh 250004, India.
Materials (Basel)
June 2023
Department of Materials Science and Engineering, National Taiwan University of Science and Technology, Taipei 106335, Taiwan.
Reduced graphene oxide (rGO) has been used in copper (II) oxide (CuO)-based photocatalysts as an additive material. An application of this CuO-based photocatalyst is in the CO reduction process. The preparation of rGO by a Zn-modified Hummers' method has resulted in a high quality of rGO in terms of excellent crystallinity and morphology.
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