The magnetic circularly polarized luminescence (MCPL) and photoluminescence (PL) spectra of achiral (2,3,7,8,12,13,17,18-octaethylporphyrinato)platinum(II), PtOEP, and [2-(4',6'-difluorophenyl)pyridinato-N,C ]platinum(II) acetylacetonate-O,O, F -ppyPt(acac), in toluene and dichloromethane solutions were recorded under an external magnetic field of 1.6 T with N-up and S-up Faraday geometries. The MCPL signs of PtOEP and F -ppyPt(acac) were controlled solely by changing the N-up and S-up geometries. The MCPL/PL wavelengths of F -ppyPt(acac) in solutions were varied by the ratio of the monomeric and excimeric species.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/asia.202100172 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
1.5D Chiral Perovskites Mediated by Hydrogen-Bonding Network with Remarkable Spin-Polarized Property.
Angew Chem Int Ed Engl
January 2025
School of Science, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China.
In this study, we developed new chiral hybrid perovskites, (R/S-MBA)(GA)PbI, by incorporating achiral guanidinium (GA) and chiral R/S-methylbenzylammonium (R/S-MBA) into the perovskite framework. The resulting materials possess a distinctive structural configuration, positioned between 1D and 2D perovskites, which we describe as 1.5D.
View Article and Find Full Text PDFSpin polarization detection via chirality-induced tunnelling currents in indium selenide.
Nat Mater
January 2025
Institute of Electrical and Microengineering, École Polytechnique Fédérale de Lausanne (EPFL), Lausanne, Switzerland.
Chirality, a basic property of symmetry breaking, is crucial for fields such as biology and physics. Recent advances in the study of chiral systems have stimulated interest in the discovery of symmetry-breaking states that enable exotic phenomena such as spontaneous gyrotropic order and superconductivity. Here we examine the interaction between light chirality and electron spins in indium selenide and study the effect of magnetic field on emerging tunnelling photocurrents at the Van Hove singularity.
View Article and Find Full Text PDFSpin and valley dependent transport and tunneling magnetoresistance in irradiated ferromagnetic WSedouble barrier junctions.
Sci Rep
January 2025
College of Science, Xuchang University, Xuchang, 461000, China.
Spin and valley polarizations (P and P) and tunneling magnetoresistance (TMR) are demonstrated in the ferromagnetic/barrier/normal/barrier/ferromagnetic WSe junction, with the gate voltage and off-resonant circularly polarized light (CPL) applied to the two barrier regions. The minimum incident energy of non-zero spin- and valley-resolved conductance has been derived, which is consistent with numerical calculations and depends on the electric potential U, CPL intensity ΔΩ, exchange field h, and magnetization configuration: parallel (P) or antiparallel (AP). For the P (AP) configuration, the energy region with P = -1 or P = 1 is wider (narrower) and increases with ΔΩ.
View Article and Find Full Text PDFNear-Infrared Magnetic Circularly Polarized Luminescence and Slow Magnetic Relaxation in a Tetrazinyl-Bridged Erbium Metallocene.
J Am Chem Soc
January 2025
Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada.
The magnetic and magneto-optical properties of a tetrazinyl radical-bridged Er metallocene, [(Cp*Er)(bpytz)][BPh] (; Cp* = pentamethylcyclopentadienyl, bpytz = 3,6-bis(3,5-dimethyl-pyrazolyl)-1,2,4,5-tetrazine), are reported. As confirmed by these studies strong Ln-rad coupling is achieved, with exhibiting slow magnetic relaxation under a 1000 Oe dc field. The optical and magneto-optical profile of is completed by both near-infrared (NIR) luminescence and magnetic circularly polarized luminescence (MCPL), representing the first example of NIR MCPL with Er.
View Article and Find Full Text PDFHigh-Performance Circular Polarization Multiple-Resonance TADF Molecules with Enhanced Long-Range Charge Transfer Based on Chiral Paracyclophane.
J Phys Chem Lett
January 2025
State Key Laboratory of Organic Electronics and Information Displays, Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, P. R. China.
Circularly polarized multiple-resonance thermally activated delayed fluorescence (CP-MR-TADF) materials have received widespread attention in recent years, but it remains a formidable challenge to design high-performance CP-MR-TADF emitters concurrently exhibiting high quantum efficiency, narrowband emission, and high dissymmetry factor (). Here, we perform an in-depth theoretical investigation on the CP-MR-TADF materials based on [2.2] paracyclophane (pCp) derivatives.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!