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Valorization of Click-Based Microporous Organic Polymer: Generation of Mesoionic Carbene-Rh Species for the Stereoselective Synthesis of Poly(arylacetylene)s. | LitMetric
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Valorization of Click-Based Microporous Organic Polymer: Generation of Mesoionic Carbene-Rh Species for the Stereoselective Synthesis of Poly(arylacetylene)s.

Kyoungil Cho Hee-Seong Yang In-Hwan Lee Sang Moon Lee Hae Jin Kim Seung Uk Son

J Am Chem Soc

Department of Chemistry, Sungkyunkwan University, Suwon 16419, Korea.

Published: March 2021

This work reports the functionalization of azide-alkyne click-based microporous organic polymer (CMOP). The generation of triazolium salts and successive deprotonation induced mesoionic carbene species in hollow CMOP (H-CMOP). Rh(I) species could be coordinated to the mesoionic carbene species to form H-CMOP-Rh, showing excellent heterogeneous catalytic performance in the stereoselective polymerization of arylacetylenes.

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http://dx.doi.org/10.1021/jacs.0c13286DOI Listing

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