Extruded PLA Nanocomposites Modified by Graphene Oxide and Ionic Liquid.

Polymers (Basel)

Grupo de Ciencia de Materiales e Ingeniería Metalúrgica, Universidad Politécnica de Cartagena, Campus de la Muralla del Mar., 30202 Cartagena, Spain.

Published: February 2021

Polylactic acid (PLA)-based nanocomposites were prepared by twin-screw extrusion. Graphene oxide (GO) and an ionic liquid (IL) were used as additives separately and simultaneously. The characterization of the samples was carried out by means of Fourier transform infrared (FT-IR) and Raman spectroscopies, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The viscoelastic behavior was determined using dynamic mechanical analysis (DMA) and rheological measurements. IL acted as internal lubricant increasing the mobility of PLA chains in the solid and rubbery states; however, the effect was less dominant when the composites were melted. When GO and IL were included, the viscosity of the nanocomposites at high temperatures presented a quasi-Newtonian behavior and, therefore, the processability of PLA was highly improved.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7926343PMC
http://dx.doi.org/10.3390/polym13040655DOI Listing

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