Preparation and Electrical Properties of Silicone Composite Films Based on Silver Nanoparticle Decorated Multi-Walled Carbon Nanotubes.

Materials (Basel)

Department of Chemical and Biological Engineering, Hanbat National University, 125 Dongseo-daero, Yuseong-gu, Daejeon 34158, Korea.

Published: February 2021

The electrical properties of silicone composite films filled with silver (Ag) nanoparticle-decorated multi-walled carbon nanotubes (MWNT) prepared by solution processing are investigated. Pristine MWNT is oxidized and converted to the acyl chloride-functionalized MWNT using thionyl chloride, which is subsequently reacted with amine-terminated poly(dimethylsiloxane) (APDMS). Thereafter, APDMS-modified MWNT are decorated with Ag nanoparticles and then reacted with a poly(dimethylsiloxane) solution to form Ag-decorated MWNT silicone (Ag-decorated MWNT-APDMS/Silicone) composite. The morphological differences of the silicone composites containing Ag-decorated MWNT and APDMS-modified MWNT are observed by transmission electron microscopy (TEM) and the surface conductivities are measured by the four-probe method. Ag-decorated MWNT-APDMS/Silicone composite films show higher surface electrical conductivity than MWNT/silicone composite films. This shows that the electrical properties of Ag-decorated MWNT-APDMS/silicone composite films can be improved by the surface modification of MWNT with APDMS and Ag nanoparticles, thereby expanding their applications.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7923106PMC
http://dx.doi.org/10.3390/ma14040948DOI Listing

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