This article aims to study the non-Fickian water absorption process in vegetable fiber-reinforced polymer composite using the Langmuir-type model, evaluating the influence of mass diffusivity on the process. The numerical solutions of the governing equations were obtained using the finite-volume method. Transient results of the local and average moisture content, free and entrapped water molecules concentration considering the constant diffusivity and as a function of the average and local moisture content were presented and analyzed. It was observed that the mass diffusivity effectively influences the water absorption behavior, especially in the initial time of the process, where higher differences in the water migration rates into the material are found. The largest free and entrapped water molecule concentration gradients were found close to the composite surface, especially when considering constant mass diffusivity.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7957561 | PMC |
http://dx.doi.org/10.3390/polym13050761 | DOI Listing |
Int J Biol Macromol
December 2024
School of Agriculture, Food and Ecosystem Sciences, Faculty of Science, The University of Melbourne, Parkville, Vic 3010, Australia. Electronic address:
This work examined the effects of molecular weight (2-15 kDa) and concentration (10-30 mg/mL) of chitosan (CTS) on the binding capacity and interface behavior between octenyl succinic acid sodium starch (OSS) and CTS, as well as their effects on the storage stability of emulsions. The results of the isothermal calorimetry titration demonstrated that OSS and CTS were complexed by electrostatic interaction and spontaneous hydrogen bonding driven by enthalpy (ΔH from -3931 to -7983 cal/mol, ΔS from -38.5 to -49.
View Article and Find Full Text PDFPlant Commun
December 2024
National Key Laboratory of Plant Molecular Genetics, CAS Center for Excellence in Molecular Plant Sciences, Shanghai Institute of Plant Physiology and Ecology, Chinese Academy of Sciences, Shanghai 200032, China. Electronic address:
Transition metals are a type of metal with high chemical activity and play critical roles in plant growth and development, reproduction and environmental adaptation, as well as for human health. However, the acquisition, transportation and storage of these metals always pose specific challenges due to their nature of high reactivity and poor solubility. In addition, distinct yet interconnected apoplastic and symplastic diffusion barriers impede their movement throughout the plants.
View Article and Find Full Text PDFPurpose: This study investigates the capabilities of ultrasonography (US) in determing the stage of orbital inflammation in patients with granulomatosis with polyangiitis (GPA).
Material And Methods: The study included 24 patients (8 men and 16 women) with diffuse orbital tissue involvement in GPA. Group 1 (active stage) included nine patients, while group 2 (inactive stage) consisted of 18 patients.
Gels
December 2024
Department of Industrial Engineering, University of Salerno, 84084 Fisciano, Italy.
Polyelectrolyte hydrogels are smart materials whose swelling behavior is governed by ionizable groups on their polymeric chains, making them sensitive to pH and ionic strength. This study combined experiments and modeling to characterize anionic hydrogels. Mechanical tests and gravimetric analyses were performed to track hydrogel mass over time and at a steady state under varying pH and salt concentrations.
View Article and Find Full Text PDFInt J Heat Mass Transf
March 2024
Department of Mechanical and Aerospace Engineering, University of California, Los Angeles, CA 90095, United States of America.
In classical theory, heat conduction in solids is regarded as a diffusion process driven by a temperature gradient, whereas fluid transport is understood as convection process involving the bulk motion of the liquid or gas. In the framework of theory, which is directly built upon quantum mechanics without relying on measured parameters or phenomenological models, we observed and investigated the fluid-like convective transport of energy carriers in solid heat conduction. Thermal transport, carried by phonons, is simulated in graphite by solving the Boltzmann transport equation using a Monte Carlo algorithm.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!