3D printing has a significant impact on various applications as it facilitates greater control over the designed shapes, leads to rapid prototyping and mass production with transferable designs at a lower cost. These attributes provide great versatility and thus make the devices industry-friendly. Herein, we demonstrate a simple and disposable 3D printed device, fabricated in single-step, as an electrochemical nitrite sensor using commercially available carbon loaded polylactic acid (PLA) filament. Nitrite, usually ingested through water and food, can be harmful when taken in excess. Thus, its efficient and accurate on-site detection becomes imperative. The device showed appreciable sensitivity and good selectivity towards nitrite having a limit-of-detection (LOD) of [Formula: see text]. Furthermore, the device has been shown to monitor nitrite in real soil and water samples with appreciable recovery values. Eventually, the device is capable to be multiplexed with varying soil parameters.

Download full-text PDF

Source
http://dx.doi.org/10.1109/TNB.2021.3063730DOI Listing

Publication Analysis

Top Keywords

electrochemical nitrite
8
nitrite
5
device
5
highly sensitive
4
sensitive interference-free
4
interference-free electrochemical
4
nitrite detection
4
detection printed
4
printed miniaturized
4
miniaturized device
4

Similar Publications

The photoelectrochemical (PEC) urea oxidation reaction (UOR) presents a promising half-reaction for green hydrogen production, but the stable resonance structure of the urea molecule results in sluggish kinetics for breaking the C-N bond. Herein, we realize the record PEC UOR performance on a NiO-modified n-Si photoanode (NiO@Ni/n-Si) by harnessing the adsorbate-adsorbate interaction. We quantificationally unveil a dependence of the UOR activation barrier on the coverage of photogenerated surface high-valent Ni-oxo species (NiIV=O) by employing operando PEC spectroscopic measurements and theoretical simulations.

View Article and Find Full Text PDF

Crystalline γ-FeO(OH) dominantly possessing ─OH terminals (𝛾-FeO(OH)), polycrystalline γ-FeO(OH) containing multiple ─O, ─OH, and Fe terminals (𝛾-FeO(OH)), and α-FeO majorly containing ─O surface terminals are used as electrocatalysts to study the effect of surface terminals on electrocatalytic nitrate reduction reaction (eNORR) selectivity and stabilization of reaction intermediates. Brunauer-Emmett-Teller analysis and electrochemically determined surface area suggest a high active surface area of 117.79 m g (ECSA: 0.

View Article and Find Full Text PDF

This paper describes the first use of conductive metal-organic frameworks as the active material in the electrochemical detection of nitric oxide in aqueous solution. Four hexahydroxytriphenylene (HHTP)-based MOFs linked with first-row transition metal nodes (M = Co, Ni, Cu, Zn) were compared as thin-film working electrodes for promoting oxidation of NO using voltammetric and amperometric techniques. Cu- and Ni-linked MOF analogs provided signal enhancement of 5- to 7-fold over a control glassy carbon electrode (SA = 6.

View Article and Find Full Text PDF

In this study, a Cu@Ag core-shell was synthesized using a co-precipitation method. To create a new electrochemical sensor, a Cu@Ag core-shell with conductive polymers such as polyalizarin yellow R (PA) and Nafion (Nf) was immobilized on the surface of a glassy carbon electrode (Cu@Ag-Nf/PA/GCE). X-ray diffraction analysis (XRD), energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), and Fourier Transform Infrared Spectroscopy (FTIR) techniques were employed to characterize the Cu@Ag-Nf/PA/GCE.

View Article and Find Full Text PDF

Three-dimensional CeO Nanosheets/CuO nanoflowers p-n heterostructure supported on carbon cloth as electrochemical sensor for sensitive nitrite detection.

Anal Chim Acta

January 2025

State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun, 130000, PR China. Electronic address:

Nitrite is widely used as a food additive, and it is of great significance to realize accurate detection of nitrite for food safety. Electrochemical technique is characterized by simple operation and portability, which enables rapid and accurate detection. The key factors affecting the nitrite detection performance are the electrocatalytic activity and interfacial electron transfer efficiency of the electrode.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!