3D printing has a significant impact on various applications as it facilitates greater control over the designed shapes, leads to rapid prototyping and mass production with transferable designs at a lower cost. These attributes provide great versatility and thus make the devices industry-friendly. Herein, we demonstrate a simple and disposable 3D printed device, fabricated in single-step, as an electrochemical nitrite sensor using commercially available carbon loaded polylactic acid (PLA) filament. Nitrite, usually ingested through water and food, can be harmful when taken in excess. Thus, its efficient and accurate on-site detection becomes imperative. The device showed appreciable sensitivity and good selectivity towards nitrite having a limit-of-detection (LOD) of [Formula: see text]. Furthermore, the device has been shown to monitor nitrite in real soil and water samples with appreciable recovery values. Eventually, the device is capable to be multiplexed with varying soil parameters.
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http://dx.doi.org/10.1109/TNB.2021.3063730 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Institute of Chemistry CAS: Institute of Chemistry Chinese Academy of Sciences, Beijing National Laboratory for Molecular Sciences, Zhongguancun North First St, 100190, Beijing, CHINA.
The photoelectrochemical (PEC) urea oxidation reaction (UOR) presents a promising half-reaction for green hydrogen production, but the stable resonance structure of the urea molecule results in sluggish kinetics for breaking the C-N bond. Herein, we realize the record PEC UOR performance on a NiO-modified n-Si photoanode (NiO@Ni/n-Si) by harnessing the adsorbate-adsorbate interaction. We quantificationally unveil a dependence of the UOR activation barrier on the coverage of photogenerated surface high-valent Ni-oxo species (NiIV=O) by employing operando PEC spectroscopic measurements and theoretical simulations.
View Article and Find Full Text PDFSmall
January 2025
Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi, Delhi, 110016, India.
Crystalline γ-FeO(OH) dominantly possessing ─OH terminals (𝛾-FeO(OH)), polycrystalline γ-FeO(OH) containing multiple ─O, ─OH, and Fe terminals (𝛾-FeO(OH)), and α-FeO majorly containing ─O surface terminals are used as electrocatalysts to study the effect of surface terminals on electrocatalytic nitrate reduction reaction (eNORR) selectivity and stabilization of reaction intermediates. Brunauer-Emmett-Teller analysis and electrochemically determined surface area suggest a high active surface area of 117.79 m g (ECSA: 0.
View Article and Find Full Text PDFACS Sens
January 2025
Department of Chemistry, Burke Laboratories, Dartmouth College, 41 College St., Hanover, New Hampshire 03755, United States.
This paper describes the first use of conductive metal-organic frameworks as the active material in the electrochemical detection of nitric oxide in aqueous solution. Four hexahydroxytriphenylene (HHTP)-based MOFs linked with first-row transition metal nodes (M = Co, Ni, Cu, Zn) were compared as thin-film working electrodes for promoting oxidation of NO using voltammetric and amperometric techniques. Cu- and Ni-linked MOF analogs provided signal enhancement of 5- to 7-fold over a control glassy carbon electrode (SA = 6.
View Article and Find Full Text PDFHeliyon
January 2025
Environmental Health Research Center, Research Institute for Health Development, Kurdistan University of Medical Sciences, Sanandaj, Iran.
In this study, a Cu@Ag core-shell was synthesized using a co-precipitation method. To create a new electrochemical sensor, a Cu@Ag core-shell with conductive polymers such as polyalizarin yellow R (PA) and Nafion (Nf) was immobilized on the surface of a glassy carbon electrode (Cu@Ag-Nf/PA/GCE). X-ray diffraction analysis (XRD), energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), and Fourier Transform Infrared Spectroscopy (FTIR) techniques were employed to characterize the Cu@Ag-Nf/PA/GCE.
View Article and Find Full Text PDFAnal Chim Acta
January 2025
State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun, 130000, PR China. Electronic address:
Nitrite is widely used as a food additive, and it is of great significance to realize accurate detection of nitrite for food safety. Electrochemical technique is characterized by simple operation and portability, which enables rapid and accurate detection. The key factors affecting the nitrite detection performance are the electrocatalytic activity and interfacial electron transfer efficiency of the electrode.
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