This study concerns the synthesis of biocomposites with kraft lignin, investigation of their physicochemical properties, and tests of their resistance to environmental factors such as UV irradiation and water. The biocomposites were synthesized using bisphenol A glycerolate (1 glycerol/phenol) diacrylate (BPA.DA) as a main monomer, ethylene glycol dimethacrylate (EGDMA) as a reactive diluent, and kraft lignin (L) as an environmentally friendly filler, in a UV curing process. Morphological analysis of the resulting materials was carried out using scanning electron microscopy and confocal microscopy. Thermal properties were investigated using thermogravimetric analysis. Tensile and flexural tests were performed for all obtained materials. Additionally, the wettability and swelling of the obtained composite samples were analyzed. The changes observed in the structure and properties of the polymers as a result of aging were investigated by means of ATR-FTIR analysis, optical profilometry and hardness tests. The results obtained regarding the effect of lignin addition on the properties of composite materials, with particular emphasis on their resistance to environmental factors, may be of crucial importance for their further applications, inter alia as UV-curable coating materials.
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http://dx.doi.org/10.1016/j.ijbiomac.2021.02.193 | DOI Listing |
Environ Res
January 2025
Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology, Tianjin 300457, P.R. China.
Herein, a biochar-supported zero-valent iron (ZVI) nanosheet catalyst (Fe@BC) for the activation of persulfate to degrade ciprofloxacin (CIP) was prepared using industrial kraft lignin and Fenton sludge as carbon and iron sources, respectively. Fe@BC showed considerably better CIP degradation efficiency (96.9% at 20 mg·L) than traditional catalysts.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Institute of Hybrid Materials, National Center of International Research for Hybrid Materials Technology, National Base of International Science & Technology Cooperation, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, China. Electronic address:
Self-supported hardwood kraft lignin (HKL)/graphene-based carbon fibrous aerogel (L/GCA) presents a fascinating prospect as the electrode of supercapacitor due to its impress rate capacity and cyclic stability. However, the hydrophobicity nature of L/GCA hampers the ion transfer between the electrode and electrolyte, thereby limiting its electrochemical performance. To address this, we enhanced the electrochemical performance of L/GCA through boron doping based on the improvement of hydrophilicity and the re-arrangement of electron density.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Research Division for Sustainable Papermaking & Advanced Materials, Key Laboratory of Biobased Materials Science and Technology (Ministry of Education), Northeast Forestry University, Harbin 150040, China. Electronic address:
In this paper, cellulose-lignin films containing Fe were prepared by the codissolution-precipitation method, and the films have high transparency as well as high UV absorption. In this process, kraft lignin chelates with Fe and then bonds with cellulose through hydrogen bonding, evenly distributing within the film. The morphological results showed that the kraft lignin chelated with Fe bound tightly linked to cellulose within the Fe@cellulose-lignin composite films.
View Article and Find Full Text PDFACS Omega
December 2024
Programa de Engenharia de Processos Químicos e Bioquímicos, Escola de Química, Centro de Tecnologia, Universidade Federal Do Rio de Janeiro, Av. Athos da Silveira Ramos, 149, Bloco E, Ilha do Fundão, Rio de Janeiro 21941-909, Brasil.
This work explored the chemical modification of lignin with succinic acid for the first time. Temperature is crucial for the process, reducing reaction time and increasing conversion. In particular, at 160 °C for five h with 0.
View Article and Find Full Text PDFData Brief
December 2024
RISE PFI AS, Høgskoleringen 6B, 7491 Trondheim, Norway.
This data article summarizes the material properties of some added-lignin thermoformed pulps (ALTPs). This type of molded pulp is particularly suited for replacing plastics in environments, where moisture is encountered, as the lignin reduces the transport and adsorption of water. The dataset was measured on wet formed substrates with either softwood chemi-thermomechanical pulp (CTMP) or northern bleached softwood Kraft pulp (NBSK).
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