A formal enone α-arylation is described. This metal-free transformation relies on the I(III)-mediated skeletal reorganization of silyl enol ethers and features mild conditions, good yields, and high stereoselectivities for β-substituted enones.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7985840PMC
http://dx.doi.org/10.1021/acs.orglett.1c00251DOI Listing

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