A catalytic 1,1-difunctionalization of unactivated olefins en route to sp bis-organometallic B,B(Si)-reagents is described. The protocol is characterized by exceptional reaction rates, mild conditions, wide scope, and exquisite selectivity pattern, constituting a new platform to access sp bis-organometallics.
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| http://dx.doi.org/10.1002/anie.202100810 | DOI Listing |
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