Date kernels (DK) are cheap by-products rich in energy and phenolic compounds. It can be used as an alternative to the conventional sources of energy in ruminant diets while reducing methane (CH) production. Using a semi-automated gas production (GP) system, the initial pH of buffered rumen liquor was adjusted to 5.5 and 6.8. Five experimental diets were evaluated, control (0% DK), and DK, DK, DK and DK presented 25, 50, 75, and 100% replacement of maize by DK, respectively. Of the 16 phenolic compounds detected in DK, protocatechuic, -hydroxybenzoic and catechin were the most abundant. At pH 6.8, the control diet recorded higher ( < 0.05) GP values throughout the first 12 h incubation than all other DK diets, while at 5.5 pH, DK displayed the highest ( < 0.05) GP at 3 and 6 h compared to all other diets. At either pH conditions, all DK diets reduced ( < 0.05) CH compared to the control without affecting protozoal counts. At 5.5 pH, DK diets showed enhanced ( < 0.05) nutrients degradability compared to control. DK modified (P < 0.05) the fermentation patterns toward more propionate than the control under either pH conditions. Substitution of maize by 50% DK was highly recommended in ruminant diets.
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http://dx.doi.org/10.1080/10495398.2021.1886941 | DOI Listing |
J Environ Manage
January 2025
School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing, 100083, China.
The cultivation of edible mushrooms plays a significant role in revitalizing numerous rural regions in China. However, this process generates a large amount of spent mushroom substrate (SMS). Traditional methods for handling SMS, such as random stacking and incineration, lead to resource waste and environmental pollution.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Martin-Luther-Universitat Halle-Wittenberg, Department of Chemistry, Kurt-Mothes-Str. 2, 06120, Halle, GERMANY.
A pronounced nucleophilicity in combination with a distinct redox non-innocence is a unique feature of a coordinated ligand, which in the current case, leads to unprecedented carbon-centered reactivity patterns: A carbodiphosphorane-based (CDP) pincer-type rhodium complex allows to cleave two C-Cl-bonds of geminal dichlorides via two consecutive SN2-type oxidative additions resulting in the formation of a stabilized carbene fragment. In the presence of a suitable reductant the carbene fragment can even be converted into olefines or hydrodehalogenation products in a catalytic reaction. The developed method can also be used to convert chlorofluorocarbons (CFCs) such as CH2ClF to fluoromethane and methane.
View Article and Find Full Text PDFEnviron Res
January 2025
School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China. Electronic address:
The pressing necessity to mitigate climate change and decrease greenhouse gas emissions has driven the advancement of heterostructure-based photocatalysts for effective CO₂ reduction. This study introduces a novel heterojunction photocatalyst formed by integrating potassium-doped polymeric carbon nitride (KPCN) with metallic Zn₃N₂, synthesized via a microwave-assisted molten salt method. The resulting Schottky contact effectively suppresses the reverse diffusion of electrons, achieving spatial separation of photogenerated charges and prolonging their lifetime, which significantly enhances photocatalytic activity and efficiency.
View Article and Find Full Text PDFSci Total Environ
January 2025
Program of Sustainability in Biosystems, Institute of Agrifood Research and Technology (IRTA), Caldes de Montbui, Barcelona, Spain. Electronic address:
Paddy fields are a major anthropogenic source of global methane (CH) emissions, a powerful greenhouse gas (GHG). This study aimed at gaining insights of different organic and inorganic conductive materials (CMs) - biochar, fungal melanin, and magnetite - to mitigate CH emissions, and on their influence on key microbial populations, mimicking the postharvest season throughout the degradation of rice straw in microcosms under anaerobic conditions encompassing postharvest paddy rice soils from the Ebro Delta, Spain. Results showed that fungal melanin was the most effective CM, significantly reducing CH emissions by 29 %, while biochar amendment also reduced emissions by 10 %.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Institute of Materials, China Academy of Engineering Physics, Jiangyou 621908, China.
Solar-driven dry reforming of methane (DRM) offers a milder, more cost-effective, and promising environmentally friendly pathway compared to traditional thermal catalytic DRM. Numerous studies have extensively investigated inexpensive Ni-based catalysts for application in solar-driven DRM. However, these catalysts often suffer from activity loss due to carbon accumulation.
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