Vibrational model of thermal conduction for fluids with soft interactions.

A vibrational model of heat transfer in simple liquids with soft pairwise interatomic interactions is discussed. A general expression is derived, which involves an averaging over the liquid collective mode excitation spectrum. The model is applied to quantify heat transfer in a dense Lennard-Jones liquid and a strongly coupled one-component plasma. Remarkable agreement with the available numerical results is documented. A similar picture does not apply to the momentum transfer and shear viscosity of liquids.