Structural characterization and statistical properties of jammed soft ellipsoid packing.

Soft Matter

Shanghai Key Laboratory of Magnetic Resonance, Institute of Materials, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, P. R. China.

Published: March 2021

AI Article Synopsis

  • The study investigates the jamming transition and packing structures of hydrogel soft ellipsoids using magnetic resonance imaging techniques, focusing on changes in fluctuations as packing fractions increase.
  • As the packing fraction rises, local free volume fluctuations decrease while particle deformation fluctuations increase, but key thermodynamic measures, like granular temperatures and configurational entropy, remain nearly constant.
  • The unique behaviors seen in these soft ellipsoids differ from hard sphere systems due to a statistically affine structural transformation occurring alongside particle deformations when the packing fraction changes.

Article Abstract

The jamming transition and jammed packing structures of hydrogel soft ellipsoids are studied using magnetic resonance imaging techniques. As the packing fraction increases, the fluctuation of local free volume decreases and the fluctuation of particle deformation increases. Effective thermodynamic quantities are obtained by characterizing these fluctuations using k-gamma distributions based on an underlying statistical model for granular materials. Surprisingly, the two granular temperatures measuring the relative fluctuations of both free volume and particle deformation remain basically unchanged as the packing fraction increases. The total configurational entropy is also approximately constant for packing with different packing fractions. The significantly different behaviors of these effective thermodynamic quantities compared with hard sphere systems are further attributed to a statistically affine structural transformation of the packing structures along with particle deformations when the packing fraction changes.

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Source
http://dx.doi.org/10.1039/d0sm01699cDOI Listing

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