Layering AgNO in alcohol onto octavinylsilsesquioxane (OVS) in CHCl results in a one-dimensional coordination polymer, {Ag(NO)(OVS)·solvents} (), consisting of unprecedented flat weakly bonded Ag(NO) alternating with the firmly covalent OVS through Ag-π bonds. The preferential assembling medium for is proven to be alcohols, where a 4:1 silver-OVS adduct is detected by electrospray ionization mass spectrometry. The present outcomes may assist our knowledge of particular interactions for supramolecular architectures of a polynuclear silver system built from OVS containing eight pendent olefin tails.
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Silica-Organometallic One-Dimensional Hybrid Employing a Ag-π Bond Connecting Alternating Ag(NO) and Octavinylsilsesquioxane.
Inorg Chem
March 2021
Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong University, Ji'nan 250100, People's Republic of China.
Layering AgNO in alcohol onto octavinylsilsesquioxane (OVS) in CHCl results in a one-dimensional coordination polymer, {Ag(NO)(OVS)·solvents} (), consisting of unprecedented flat weakly bonded Ag(NO) alternating with the firmly covalent OVS through Ag-π bonds. The preferential assembling medium for is proven to be alcohols, where a 4:1 silver-OVS adduct is detected by electrospray ionization mass spectrometry. The present outcomes may assist our knowledge of particular interactions for supramolecular architectures of a polynuclear silver system built from OVS containing eight pendent olefin tails.
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