Co-adsorption of As(III) and phenanthrene by schwertmannite and Fenton-like regeneration of spent schwertmannite to realize phenanthrene degradation and As(III) oxidation.

Co-contamination of arsenic and polycyclic aromatic hydrocarbons (PAHs) in groundwater is frequently reported, and it is thus necessary to develop efficient techniques to tackle this problem. Here, we evaluated the feasibility of utilizing schwertmannite to co-adsorb As(III) and phenanthrene from water solution and regenerating spent schwertmannite via a heterogeneous Fenton-like reaction to degrade adsorbed phenanthrene and meanwhile oxidize adsorbed As(III). The results suggested that schwertmannite with a hedgehog-like morphology was superior to that with a smooth surface for the adsorption removal of As(III) or phenanthrene because of the much higher BET surface area and hydroxyl proportion of the former one, and schwertmannite formed at 72 h incubation effectively co-adsorbed As(III) and phenanthrene from water solution. The adsorption of As(III) and phenanthrene on schwertmannite did not interfere with each other, while the acidic initial solution pH delayed the adsorption of As(III) on schwertmannite but enhanced the adsorption capacity for phenanthrene. The adsorption of As(III) on schwertmannite mainly involved its exchange with SO (outer-sphere or inner-sphere) and its complexation with iron hydroxyl surface groups, and phenanthrene adsorption mainly occurred through cation-π bonding and OH-π interaction. During the adsorption-regeneration processes, schwertmannite adsorbed As(III) and phenanthrene firstly, and then it can be successfully regenerated via Fenton-like reaction catalyzed by itself to effectively degrade the adsorbed phenanthrene and meanwhile oxidize the adsorbed As(III) to As(V). Therefore, schwertmanite is an outstanding environmental adsorbent to decontaminate As(III) and phenanthrene co-existing in groundwater.