Coupling of adsorption and advanced oxidation processes triggered by metal-free carbocatalysts is an appealing wastewater purification scheme. However, its practical application is challenging due to the unsatisfactory stability of conventional heteroatom-doped systems. Herein, we innovatively developed a simple and scalable biochemical strategy to synthesize selenium and nitrogen co-doped biochar (Se/N-BC) as a bifunctional catalyst of adsorption-oxidation. The Se/N-BC displays the highest efficiency of phenol (PE) degradation (99.2% of PE was removed within 5 min) with the lowest dosage of catalyst (0.1 g L) and peroxymonosulfate (PMS, 0.4 g L). More importantly, the Se/N-BC is not only universal in a wide pH range of 3.0-11.0 and complex ionic environment, but also possesses an excellent cycling stability. The Se/N co-doping induces a rapid cycle of adsorption-degradation for PE. The Se/N-BC acts as an "electron transfer bridge", guiding rapid electron transfer from PE to PMS to achieve high-efficient degradation. The Se/N co-doping facilitates the formation of graphitic N and unlocks the potential of adjacent C sites for PMS activation, consequently boost oxidation efficiency. In addition, the oxidation of catalyst is prevented due to the antioxidant properties of Se, which has been a primary concern either to regenerate adsorbate or to enhance degradation performance.

Download full-text PDF

Source
http://dx.doi.org/10.1016/j.jhazmat.2021.125294DOI Listing

Publication Analysis

Top Keywords

selenium nitrogen
8
nitrogen co-doped
8
co-doped biochar
8
se/n co-doping
8
biochar metal-free
4
catalyst
4
metal-free catalyst
4
catalyst adsorption
4
adsorption phenol
4
phenol activation
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!