A steady and proper thermal environment in deep underground is imperative to ensure worker health and production safety. Understanding the thermal performance in the roadway is the premise of temperature prediction; ventilation design; and improvement in cooling efficiency. A full coupled model incorporated with a moving mesh method was adopted; reflecting the dynamic condition of roadway construction. This study revealed the characteristics of the thermal performance and its evolution law in an excavating roadway. Several scenarios were performed to examine the designs of the auxiliary ventilation system on thermal performance in the roadway. The results show that there is a limitation in the cooling effect by continuously increasing the ventilation volume. Reducing the diameter of the air duct or distances between the duct outlet and the working face will aggravate the heat hazard in the roadway. The heat release from the roadway wall increases with the increase of the advance rate of the working face or roadway section size. Furthermore; an orthogonal experiment was conducted to investigate the effect of major factors on the average air temperature and local heat accumulation in the roadway.
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http://dx.doi.org/10.3390/ijerph18031184 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Northwestern Polytechnical University, School of Chemistry and Chemical Engineering, CHINA.
The increasing power and integration of electronic devices have intensified serious heat accumulation, driving the demand for higher intrinsic thermal conductivity in thermal interface materials, such as polydimethylsiloxane (PDMS). Grafting mesogens onto PDMS can enhance its intrinsic thermal conductivity. However, the high stability of the PDMS chain limits the grafting density of mesogens, restricting the improvement in thermal conductivity.
View Article and Find Full Text PDFMetabolomics
January 2025
Owlstone Medical Ltd., Cambridge, UK.
Introduction: Breath Volatile organic compounds (VOCs) are promising biomarkers for clinical purposes due to their unique properties. Translation of VOC biomarkers into the clinic depends on identification and validation: a challenge requiring collaboration, well-established protocols, and cross-comparison of data. Previously, we developed a breath collection and analysis method, resulting in 148 breath-borne VOCs identified.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Georgia Institute of Technology, School Of Chemistry and Biochemistry, 901 Atlantic Drive, 30332, United States, 30332, Atlanta, UNITED STATES OF AMERICA.
The development of chemically recyclable polymers for sustainable 3D printing is crucial to reducing plastic waste and advancing towards a circular polymer economy. Here, we introduce a new class of polythioenones (PCTE) synthesized via Michael addition-elimination ring-opening polymerization (MAEROP) of cyclic thioenone (CTE) monomers. The designed monomers are straightforward to synthesize, scalable and highly modular, and the resulting polymers display mechanical performance superior to commodity polyolefins such as polyethylene and polypropylene.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Leibniz University Hanover: Leibniz Universitat Hannover, Institute for Solid State Physics, GERMANY.
Graphdiyne (GDY) has been considered a promising electrode material for application in electrochemical energy storage. However, studies on GDY featuring an ordered interlayer stacking are lacking, which is supposed to be another effective way to increase lithium binding sites and diffusion pathways. Herein, we synthesized a hydrogen-substituted GDY (HsGDY) with a highly-ordered AA-stacking structure via a facile alcohol-thermal method.
View Article and Find Full Text PDFNanoscale
January 2025
School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
Ammonium perchlorate (AP) is widely utilized in aerospace, defense and other fields due to its high energy density, exceptional stability, easy availability and adaptability. However, the high sensitivity and hygroscopicity of AP severely constrain its application in numerous fields. In this study, a two-step continuous coating method was employed to construct AP-based energetic microcapsules with low sensitivity and hygroscopicity.
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