The results ofHe gas pulsed NMR spin-lattice relaxation study in high-porosity (84.9%-97.9%) nematically ordered AlOaerogels at 1.5 and 4.2 K are presented. The linear dependence ofon gas pressure is observed in aerogels that are pre-plated by helium-4. Nitrogen pre-plating prior to helium-4 pre-plating weakly decreases theHe gas spin-lattice relaxation rate. A few possible mechanisms plausibly involved inHe nuclear magnetic relaxation in aerogels are considered. The suggested nuclear spin-lattice relaxation model due to some magnetically 'dirty' aerogel fibers allows to estimate the effective mean free path ofHe atoms in aerogel.
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http://dx.doi.org/10.1088/1361-648X/abe475 | DOI Listing |
ACS Mater Lett
January 2025
Department of Materials and London Centre for Nanotechnology, Imperial College London, South Kensington Campus, Exhibition Road, SW7 2AZ London, United Kingdom.
Quantum technologies using electron spins have the advantage of employing chemical qubit media with tunable properties. The principal objective of material engineers is to enhance photoexcited spin yields and quantum spin relaxation. In this study, we demonstrate a facile synthetic approach to control spin properties in charge-transfer cocrystals consisting of 1,2,4,5-tetracyanobenzene (TCNB) and acetylated anthracene.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
January 2025
William H. Miller III Department of Physics and Astronomy, The Johns Hopkins University, Baltimore, MD 21218.
Introducing an experimental technique of time-resolved inelastic neutron scattering (TRINS), we explore the time-dependent effects of resonant pulsed microwaves on the molecular magnet CrFPiv. The octagonal rings of magnetic Cr atoms with antiferromagnetic interactions form a singlet ground state with a weakly split triplet of excitations at 0.8 meV.
View Article and Find Full Text PDFNat Commun
December 2024
Department of Chemistry, School of Science and Research Center for Industries of the Future, Westlake University, Hangzhou, Zhejiang Province, China.
The solid-state integration of molecular electron spin qubits could promote the advancement of molecular quantum information science. With highly ordered structures and rational designability, microporous framework materials offer ideal matrices to host qubits. They exhibit tunable phonon dispersion relations and spin distributions, enabling optimization of essential qubit properties including the spin-lattice relaxation time (T) and decoherence time.
View Article and Find Full Text PDFACS Cent Sci
December 2024
Division of Chemistry and Chemical Engineering, Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena, California 91125, United States.
Spin-lattice relaxation constitutes a key challenge for the development of quantum technologies, as it destroys superpositions in molecular quantum bits (qubits) and magnetic memory in single molecule magnets (SMMs). Gaining mechanistic insight into the spin relaxation process has proven challenging owing to a lack of spectroscopic observables and contradictions among theoretical models. Here, we use pulse electron paramagnetic resonance (EPR) to profile changes in spin relaxation rates ( ) as a function of both temperature and magnetic field orientation, forming a two-dimensional data matrix.
View Article and Find Full Text PDFMagn Reson Med
December 2024
Center for Biomedical Imaging, Department of Radiology, New York University Grossman School of Medicine, New York, New York, USA.
Purpose: To implement and evaluate the feasibility of brain spin-lattice relaxation in the rotating frame (T1ρ) mapping using a novel optimized pulse sequence that incorporates weighted spin-lock acquisitions, enabling high-resolution three-dimensional (3D) mapping.
Methods: The optimized variable flip-angle framework, previously proposed for knee T1ρ mapping, was enhanced by integrating weighted spin-lock acquisitions. This strategic combination significantly boosts signal-to-noise ratio (SNR) while reducing data acquisition time, facilitating high-resolution 3D-T1ρ mapping of the brain.
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