A novel double-decker porphyrin complex, bis{-tetrakis(4--alkylpyridiniumyl)porphyrinato}cerium, was prepared. Electrochemical measurements revealed that this complex exhibited reversible redox waves corresponding to a 1e redox reaction of the cerium center. Treating the complex alternately with an oxidant and a reductant resulted in the reversible redox switching between the oxidized and reduced states in an organic solvent.
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| http://dx.doi.org/10.3390/molecules26040790 | DOI Listing |
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