Oriented Assembly of Anisotropic Nanosheets into Ultrathin Flowerlike Superstructures for Energy Storage.

ACS Nano

State Key Laboratory of Pollution Control and Resources Reuse, School of the Environment, Nanjing University, Nanjing 210023, China.

Published: February 2021

AI Article Synopsis

  • The study focuses on using hierarchical ultrathin nanostructures as effective electrode materials for supercapacitors due to their high surface area and enhanced ion/electron transport.
  • They explored nine l-amino acids to create CoNi-OH/l-A materials, resulting in various structures including lamellar and flower-shaped forms.
  • The ultrathin flowerlike CoNi-OH/l-asparagine showed exceptional performance, with a specific capacity of 405.4 mAh g and impressive cycling stability, while an asymmetrical supercapacitor device exhibited a strong energy density and durability over numerous cycles.

Article Abstract

The hierarchical ultrathin nanostructures are excellent electrode materials for supercapacitors because of their large surface area and their ability to promote ion and electron transport. Herein, we investigated nine l-amino acids (LAs) as inductive agents to synthesize a series of CoNi-OH/LAs materials for energy storage. With the different amino acids, the assembled CoNi-OH/LAs form a lamellar, flower-shaped, and bulk structure. Among all materials, the ultrathin flowerlike CoNi-OH/l-asparagine (CoNi-OH/l-Asn) exhibits an excellent specific capacity of 405.4 mAh g (2608 F g) and a 100% retention rate after 3000 cycles. We also assembled asymmetrical supercapacitor CoNi-OH/l-Asn//N-rGO devices, which demonstrated an energy density of 64.9 Wh kg at 799.9 W kg and superlong cycling stability (82.4% at 10 A g) over 5000 cycles.

Download full-text PDF

Source
http://dx.doi.org/10.1021/acsnano.0c08088DOI Listing

Publication Analysis

Top Keywords

ultrathin flowerlike
8
energy storage
8
oriented assembly
4
assembly anisotropic
4
anisotropic nanosheets
4
nanosheets ultrathin
4
flowerlike superstructures
4
superstructures energy
4
storage hierarchical
4
hierarchical ultrathin
4

Similar Publications

Highly-efficient and cost-effective electrocatalysts toward the oxygen evolution reaction (OER) are crucial for advancing sustainable energy technologies. Herein, a novel approach leveraging corrosion engineering is presented to facilitate the in situ growth of amorphous cobalt-iron hydroxides on nickel-iron foam (CoFe(OH)-m/NFF) within a NaCl-CoCl aqueous solution. By adjusting the concentration of the solution, the compositions can tailored and morphologies of these hydroxides to optimize the OER electrocatalytic performance.

View Article and Find Full Text PDF

Molybdenum disulfide nanoflowers (MoS NFs) were prepared by hydrothermal method. The prepared MoS NFs was characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), specific surface areas, Raman and X-ray photoelectron spectroscopy (XPS). The characterization results show that the flower-like spherical MoS is composed of many ultra-thin nanosheets with an average diameter of about 300-400 nm.

View Article and Find Full Text PDF

Flower-like Ni/Mn/MC microspheres derived from metal-organic frameworks for electrocatalytic degradation of ceftriaxone sodium.

Chemosphere

March 2024

School of Chemistry and Material Science, Heilongjiang University, Xuefu Road 74, Harbin, 150080, China. Electronic address:

This study demonstrated the design and fabrication of flower-like Ni/Mn-MOFs materials, and three-dimensional ultrathin flower-like Ni/Mn/MC microspheres were fabricated by embedding metal or metal oxide nanoparticles into a porous carbon skeleton via high-temperature pyrolysis at 600 °C and used for the electrocatalytic degradation of ceftriaxone sodium. This unique ultrathin porous flower-like structure can expose more active sites, provide rapid ion/electron transfer, and improve electrocatalytic activity. Meanwhile, the excellent electrical conductivity of the carbon skeleton, as well as the rational composition and synergistic effect of the two components, can promote the generation of active radicals (•OH and •O) in the reaction system, which accelerates the electrochemical degradation process and improves the electrocatalytic degradation performance.

View Article and Find Full Text PDF

Simultaneous Morphology and Band Structure Manipulation of BiOBr by Te Doping for Enhanced Photocatalytic Oxygen Evolution.

ACS Appl Mater Interfaces

December 2023

College of Materials Science and Engineering, Shenzhen Key Laboratory of Special Functional Materials, Shenzhen Engineering Laboratory for Advanced Technology of Ceramics, Guangdong Research Center for Interfacial Engineering of Functional Materials, Institute of Deep Underground Sciences and Green Energy, Shenzhen University, Shenzhen 518060, P. R. China.

The photocatalytic oxygen evolution of bismuth oxybromide (BiOBr) is greatly hindered by its low visible-light response and high electron-hole recombination. Nonmetal doping can effectively alleviate these issues, leading to improvement in photocatalytic performance. Herein, BiTe was introduced as both the Te doping source and the morphology-control template to improve the photocatalytic performance of BiOBr.

View Article and Find Full Text PDF

Nanosheet-assembled transition metal sulfides nanoflowers derived from CoMo-MOF for efficient oxygen evolution reaction.

J Colloid Interface Sci

January 2024

College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Renai Road, Suzhou 215123, PR China. Electronic address:

Oxygen evolution reaction (OER) is a multi-electron transfer process, whose intrinsic sluggish dynamic restricts the whole process of overall water splitting (OWS). To address this issue, a porous transition metal sulfide (TMS) catalyst with rich heterojunctions was prepared by vulcanization and trace Fe doping of CoMo-based metal-organic framework (MOF). In this work, the nanoflower composed of ultrathin 2D nanosheets anchored on a nickel foam presents a layered interface that contributes to the exposure of active regions.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!