The hierarchical ultrathin nanostructures are excellent electrode materials for supercapacitors because of their large surface area and their ability to promote ion and electron transport. Herein, we investigated nine l-amino acids (LAs) as inductive agents to synthesize a series of CoNi-OH/LAs materials for energy storage. With the different amino acids, the assembled CoNi-OH/LAs form a lamellar, flower-shaped, and bulk structure. Among all materials, the ultrathin flowerlike CoNi-OH/l-asparagine (CoNi-OH/l-Asn) exhibits an excellent specific capacity of 405.4 mAh g (2608 F g) and a 100% retention rate after 3000 cycles. We also assembled asymmetrical supercapacitor CoNi-OH/l-Asn//N-rGO devices, which demonstrated an energy density of 64.9 Wh kg at 799.9 W kg and superlong cycling stability (82.4% at 10 A g) over 5000 cycles.
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http://dx.doi.org/10.1021/acsnano.0c08088 | DOI Listing |
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November 2024
State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology (Shandong Academy of Sciences), Jinan, Shandong, 250353, P. R. China.
Highly-efficient and cost-effective electrocatalysts toward the oxygen evolution reaction (OER) are crucial for advancing sustainable energy technologies. Herein, a novel approach leveraging corrosion engineering is presented to facilitate the in situ growth of amorphous cobalt-iron hydroxides on nickel-iron foam (CoFe(OH)-m/NFF) within a NaCl-CoCl aqueous solution. By adjusting the concentration of the solution, the compositions can tailored and morphologies of these hydroxides to optimize the OER electrocatalytic performance.
View Article and Find Full Text PDFChem Biodivers
July 2024
Shandong Wolan Environmental Technologies Co., Ltd, Jinan, 250101, P. R. China.
Molybdenum disulfide nanoflowers (MoS NFs) were prepared by hydrothermal method. The prepared MoS NFs was characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), specific surface areas, Raman and X-ray photoelectron spectroscopy (XPS). The characterization results show that the flower-like spherical MoS is composed of many ultra-thin nanosheets with an average diameter of about 300-400 nm.
View Article and Find Full Text PDFChemosphere
March 2024
School of Chemistry and Material Science, Heilongjiang University, Xuefu Road 74, Harbin, 150080, China. Electronic address:
This study demonstrated the design and fabrication of flower-like Ni/Mn-MOFs materials, and three-dimensional ultrathin flower-like Ni/Mn/MC microspheres were fabricated by embedding metal or metal oxide nanoparticles into a porous carbon skeleton via high-temperature pyrolysis at 600 °C and used for the electrocatalytic degradation of ceftriaxone sodium. This unique ultrathin porous flower-like structure can expose more active sites, provide rapid ion/electron transfer, and improve electrocatalytic activity. Meanwhile, the excellent electrical conductivity of the carbon skeleton, as well as the rational composition and synergistic effect of the two components, can promote the generation of active radicals (•OH and •O) in the reaction system, which accelerates the electrochemical degradation process and improves the electrocatalytic degradation performance.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2023
College of Materials Science and Engineering, Shenzhen Key Laboratory of Special Functional Materials, Shenzhen Engineering Laboratory for Advanced Technology of Ceramics, Guangdong Research Center for Interfacial Engineering of Functional Materials, Institute of Deep Underground Sciences and Green Energy, Shenzhen University, Shenzhen 518060, P. R. China.
The photocatalytic oxygen evolution of bismuth oxybromide (BiOBr) is greatly hindered by its low visible-light response and high electron-hole recombination. Nonmetal doping can effectively alleviate these issues, leading to improvement in photocatalytic performance. Herein, BiTe was introduced as both the Te doping source and the morphology-control template to improve the photocatalytic performance of BiOBr.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2024
College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Renai Road, Suzhou 215123, PR China. Electronic address:
Oxygen evolution reaction (OER) is a multi-electron transfer process, whose intrinsic sluggish dynamic restricts the whole process of overall water splitting (OWS). To address this issue, a porous transition metal sulfide (TMS) catalyst with rich heterojunctions was prepared by vulcanization and trace Fe doping of CoMo-based metal-organic framework (MOF). In this work, the nanoflower composed of ultrathin 2D nanosheets anchored on a nickel foam presents a layered interface that contributes to the exposure of active regions.
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