A cornerstone of current-density functional theory (CDFT) in its paramagnetic formulation is proven. After a brief outline of the mathematical structure of CDFT, the lower semicontinuity and expectation-valuedness of the CDFT constrained-search functional is proven, meaning that there is always a minimizing density matrix in the CDFT constrained-search universal density functional. These results place the mathematical framework of CDFT on the same footing as that of standard DFT.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7883387 | PMC |
http://dx.doi.org/10.1021/acs.jpclett.0c03422 | DOI Listing |
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