We investigate collisional decay of the axial charge in an electron-photon plasma at temperatures 10 MeV-100 GeV. We demonstrate that the decay rate of the axial charge is first order in the fine-structure constant Γ_{flip}∝αm_{e}^{2}/T and thus orders of magnitude greater than the naive estimate which has been in use for decades. This counterintuitive result arises through infrared divergences regularized at high temperature by environmental effects. The decay of axial charge plays an important role in the problems of leptogenesis and cosmic magnetogenesis.
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http://dx.doi.org/10.1103/PhysRevLett.126.021801 | DOI Listing |
Langmuir
January 2025
Mechanical Engineering Department, Indian Institute of Technology Kharagpur, Kharagpur-721302, India.
Electrorheological fluids are suspensions that are characterized by a strong functional dependence of their constitutive behavior on the local electric field. While such fluids are known to be promising in different applications of microfluidics including electrokinetic flows, their capabilities of controlling ion transport and preferential solute segregation in confined fluidic systems remain to be explored. In this work, we bring out the unique role of electrorheological fluids in orchestrating the selective enrichment and depletion of charged species in variable area microfluidic channels.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Chemistry and Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen 518055, Guangdong, China.
Single-atom catalysts (SACs) have attracted widespread attention due to their potential to replace platinum-based catalysts in achieving efficient oxygen reduction reaction (ORR), yet the rational optimization of SACs remains challenging due to their elusive reaction mechanisms. Herein, by employing ab initio molecular dynamics simulations and a thermodynamic integration method, we have constructed the potential-dependent free energetics of ORR on a single iron atom catalyst dispersed on nitrogen-doped graphene (Fe-N/C) and further integrated these parameters into a microkinetic model. We demonstrate that the rate-determining step (RDS) of the ORR on SACs is potential-dependent rather than invariant within the operative potential range.
View Article and Find Full Text PDFNat Commun
January 2025
Department of Physics and Astronomy, Seoul National University, Seoul, Korea.
Understanding how symmetry-breaking processes generate order out of disorder is among the most fundamental problems of nature. The scalar Higgs mode - a massive (quasi-) particle - is a key ingredient in these processes and emerges with the spontaneous breaking of a continuous symmetry. Its related exotic and elusive axial counterpart, a Boson with vector character, can be stabilized through the simultaneous breaking of multiple continuous symmetries.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, 800 Dong Chuan Road, Shanghai 200240, China.
Direct harvesting of abundant solar thermal energy within organic phase-change materials (PCMs) has emerged as a promising way to overcome the intermittency of renewable solar energy and pursue high-efficiency heating-related applications. Organic PCMs, however, generally suffer from several common shortcomings including melting-induced leakage, poor solar absorption, and low thermal conductivity. Compounding organic PCMs with single-component carbon materials faces the difficulty in achieving optimized comprehensive performance enhancement.
View Article and Find Full Text PDFJ Comput Chem
January 2025
Department of Mechanical Engineering, Texas Tech University, Lubbock, Texas, USA.
Multi-copper oxidases (MCOs) are enzymes of significant interest in biotechnology due to their efficient catalysis of oxygen reduction to water, making them valuable in sustainable energy production and bio-electrochemical applications. This study employs time-dependent density functional theory (TDDFT) to investigate the electronic structure and spectroscopic properties of the Type 1 (T1) copper site in Azurin, which serves as a model for similar sites in MCOs. Four model complexes of varying complexity were derived from the T1 site, including 3 three-coordinate models and 1 four-coordinate model with axial methionine ligation, to explore the impact of molecular branches and axial coordination.
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