In the past few years, a large variety of perovskite solar cells (PSCs) with vivid and well-distinguished color hues have been demonstrated. In this Perspective, we compare different strategies employed to realize colorful PSCs both in opaque and semitransparent designs. The approaches used to modulate the PSCs' colorful appearance can be divided into two main categories: the first one based on the modifications of their internal layers (, absorber, electron- and/or hole-transporting layers, and electrodes), while the second is based on the addition of external colored or nanostructured films to the standard PSCs. The advantages and bottlenecks of each strategy are discussed in terms of PSCs' color tunability, transparency, photovoltaic performances, fabrication processes feasibility, and scalability, in view of suitable applications in an urban context for building-integrated photovoltaics.
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http://dx.doi.org/10.1021/acs.jpclett.0c03445 | DOI Listing |
Adv Sci (Weinh)
January 2025
Institute of Molecular Science, University of Valencia, c/Catedrático José Beltrán Martínez 2, Paterna, 46980, Valencia, Spain.
Energy transfer processes in nanohybrids are at the focal point of conceptualizing, designing, and realizing novel energy-harvesting systems featuring nanocrystals that absorb photons and transfer their energy unidirectionally to surface-immobilized functional dyes. Importantly, the functionality of these dyes defines the ultimate application. Herein, CsPbBr perovskite nanocrystals (NCs) are interfaced with zinc phthalocyanine (ZnPc) dyes featuring carboxylic acid.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan.
High-performance and cost-effective hole-collecting materials (HCMs) are indispensable for commercially viable perovskite solar cells (PSCs). Here, we report an anchorable HCM composed of a triazatruxene core connected with three alkyl carboxylic acid groups (). In contrast to the phosphonic acid-containing tripodal analog (), molecules can form a hydrophilic monolayer on a transparent conducting oxide surface, which is beneficial for subsequent perovskite film deposition in the traditional layer-by-layer fabrication process.
View Article and Find Full Text PDFNanomicro Lett
January 2025
The Quzhou Affiliated Hospital of Wenzhou Medical University, Quzhou People's Hospital, Quzhou, 324000, People's Republic of China.
Organic additives with multiple functional groups have shown great promise in improving the performance and stability of perovskite solar cells. The functional groups can passivate undercoordinated ions to reduce nonradiative recombination losses. However, how these groups synergistically affect the enhancement beyond passivation is still unclear.
View Article and Find Full Text PDFACS Nano
January 2025
MIIT Key Laboratory of Advanced Display Materials and Devices, Jiangsu Province Engineering Research Center of Quantum Dot Display, School of Materials Science and Engineering, Institute of Optoelectronics & Nanomaterials, Nanjing University of Science and Technology, Nanjing, Jiangsu 210094, China.
Room temperature (RT) synthesized mixed bromine and chlorine CsPbBrCl perovskite quantum dots (Pe-QDs) offer notable advantages for blue quantum dot light-emitting diodes (QLEDs), such as cost-effective processing and narrow luminescence peaks. However, the efficiency of blue QLEDs using these RT-synthesized QDs has been limited by inferior crystallinity and deep defect presence. In this study, we demonstrate a precise approach to constructing high-quality gradient core-shell (CS) structures of CsPbBrCl QD through anion exchange.
View Article and Find Full Text PDFChemSusChem
January 2025
North China Electric Power University, Changping district, NO.2, Beinong Road, CHINA.
Semitransparent perovskite solar cells (ST-PSCs) for building-integrated photovoltaics (BIPV) face the challenge of achieving high efficiency due to significant light loss. The SnO2 electron transport layer (ETL), utilized in n-i-p PSCs and prepared via the sol-gel method, is susceptible to aggregation on substrate, resulting in light scattering that diminishes absorption of the perovskite layer. In this study, we propose a strategy that combines atomic layer deposition (ALD) and sol-gel solution to deposit a bilayer SnO2 structure to address these issues.
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