Three nitrogen-rich heterocyclic compounds containing the diamino-pyrimidine mono-N-oxide moiety were synthesized via mild oxidation reactions. Oxidation of the furazano-pyrimidine compound (1) with a mixture of trifluoroacetic anhydride (TFAA) and hydrogen peroxide (50%) gave the nitrate salt (3). All of the compounds were characterized by NMR spectra, elemental analysis, and single-crystal X-ray diffraction. They show high thermal stability and good detonation performance as well as low sensitivity.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d0dt03260c | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Mono-N-oxidation of heterocycle-fused pyrimidines.
Dalton Trans
February 2021
Nanjing University of Science and Technology, Nanjing, 210094, China.
Three nitrogen-rich heterocyclic compounds containing the diamino-pyrimidine mono-N-oxide moiety were synthesized via mild oxidation reactions. Oxidation of the furazano-pyrimidine compound (1) with a mixture of trifluoroacetic anhydride (TFAA) and hydrogen peroxide (50%) gave the nitrate salt (3). All of the compounds were characterized by NMR spectra, elemental analysis, and single-crystal X-ray diffraction.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!