In this study, we investigated the distribution and chemical speciation of Se in Se-rich soil by using micro-focused X-ray absorption near-edge structure (μ-XANES) spectroscopy coupling with X-ray fluorescence (μ-XRF) mapping. The microscale distribution showed that Se is heterogeneously distributed in the soil from seleniferous areas in Enshi, China. Se K-edge μ-XANES analysis suggested that Se is mainly present as Se(IV), organic Se(-II) or Se(0) species in Se-rich agricultural soil. The findings from this study would help improve the understanding of the fate, mobility, bioavailability, and biogeochemical cycling of Se in the seleniferous soil environment.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1007/s00128-020-03090-7 | DOI Listing |
Anal Bioanal Chem
September 2024
CNRS, Institute of Analytical and Physical Chemistry for the Environment and Materials (IPREM), UMR5254, Hélioparc, Universite of Pau, 64053, Pau, France.
The complete characterization of selenium-enriched yeast in terms of selenium species has been the goal of extensive research for the last three decades. This contribution addresses the two outstanding questions: the mass balance of the identified and reported selenium species and the possible presence of inorganic selenium. For this purpose, four procedures have been designed combining, in diverse order, the principal steps of selenium speciation analysis in Se-rich yeast: extraction of the Se-metabolome, derivatization of cysteine and Se-cysteine (SeCys) residues, proteolysis, and definitive Se recovery using SDS extraction, followed by mineralization.
View Article and Find Full Text PDFSci Total Environ
November 2024
Department of Biology, Gus R. Douglass Institute, West Virginia State University, Institute, WV 25112, USA. Electronic address:
Selenium (Se) plays crucial roles in human, animal, and plant physiology, but its varied plant functions remain complex and not fully understood. While Se deficiency affects over a billion people worldwide, excessive Se levels can be toxic, presenting substantial risks to ecosystem health and public safety. The delicate balance between Se's beneficial and harmful effects necessitates a deeper understanding of its speciation dynamics and how different organisms within ecosystems respond to Se.
View Article and Find Full Text PDFInt J Mol Sci
July 2024
School of Modern Industry for Selenium Science and Engineering, Wuhan Polytechnic University, Wuhan 430023, China.
Selenium (Se)-rich is popular for its bioactive components, and exogenous Se fortification is the most effective means of enrichment. However, the effects of exogenous Se fortification on the nutritional quality of are not well known. To investigate the nutrient contents and antioxidant properties of following Se treatment, we used a foliar spray to apply Se in two forms-chemical nano-Se (Che-SeNPs) and sodium selenite (NaSeO).
View Article and Find Full Text PDFFood Chem
October 2024
National R&D Center for Se-rich Agricultural Products Processing, Hubei Engineering Research Center for Deep Processing of Green Se-rich Agricultural Products, School of Modern Industry for Selenium Science and Engineering, Wuhan Polytechnic University, Wuhan 430023, China; Key Laboratory for Deep Processing of Major Grain and Oil, Ministry of Education, Hubei Key Laboratory for Processing and Transformation of Agricultural Products, Wuhan Polytechnic University, Wuhan 430023, PR China. Electronic address:
Selenoproteins found in selenium (Se)-enriched vegetables play a vital role in maintaining human health. In this study, four Se-containing broccoli proteins (Se-BP: albumin, globulin, prolamin, and glutelin) were continuous extracted by Osborne method. Three ultrafiltered fractions were subsequently obtained from the glutelin hydrolysate, composed of Se-contained broccoli peptides (Se-Bp) with different molecular weights (M), namely, < 1 kDa, 1-3 kDa, and 3-10 kDa.
View Article and Find Full Text PDFEnviron Sci Technol
January 2023
School of Environmental Studies, China University of Geosciences, 430074 Wuhan, China.
Mollisols support the most productive agroecosystems in the world. Despite their critical links to food quality and human health, the varying distributions of selenium (Se) species and factors governing Se mobility in the mollisol vadose zone remain elusive. This research reveals that, in northern mollisol agroecosystems, Se hotspots (≥0.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!