Synthesis and Characterization of New Mesoporous Polyurethane-Nitrogen Doped Carbon Dot Nanocomposites: Ultrafast, Highly Selective and Sensitive Turn-off Fluorescent Sensors for Fe Ions.

A new fluorescent mesoporous polyurethane (PU) (9) was synthesized by reaction between 2,2'-(methylenebis(4,1-phenylene))bis(5-isocyanatoisoindoline-1,3-dione) (Diisocyanate) (5) and 4,4',4″-((1,3,5-triazine-2,4,6-triyl)tris (azanediyl))triphenol (Triol, TO) (8) (molar ratio 3:2). PU was characterized by using FT-IR, H-NMR, XRD, UV-Vis, TGA, Nitrogen adsorption-desorption isotherm, BET, FE-SEM and Photoluminescence (PL) analyses. To the best of our knowledge, this is the first time that a fluorescent polyurethane has been made without the use of commercial fluorescent materials. PU has high fluorescent intensity and it is ultrafast (about few seconds), highly selective and sensitive turn-off fluorescent sensor for Fe ions. This chemosensor exhibited a wide concentration range of (10-250)×10 M Fe with quenching efficiency (η) 97.50%. Limit of detection (LOD), limit of quantification (LOQ) and quenching constant (Ksv) values were calculated 10.10×10 M, 30.60×10 M and 6919.31 M, respectively. Nitrogen doped carbon dots (N-doped CDs) as fluorescent nanoparticles and with the aim of improving Fe detecting were synthesized by microwave-assisted and using citric acid monohydrate (10) and ethylenediamine (11) as carbon and nitrogen sources, respectively. Fluorescent nanocomposites (FNCs) were prepared by using casting and in-situ methods. In both methods, two nanocomposites containing 5 and 10%w of N-doped CDs were prepared. FNCs were characterized by using FT-IR, UV-Vis, XRD, TGA, Nitrogen adsorption-desorption isotherm, BET, FE-SEM and PL analyses. All nanocomposites showed better thermal property and sensitivity and lower LOD values in lower concentration of Fe related to PU. Among them, FNC10in exhibited the best results as η, LOD, LOQ, Ksv reached 99.80%, 1.15×10 M, 3.48×10 M and 53,551.48 M, respectively.