Symmetric and asymmetric epitaxial growth of metals (Ag, Pd, and Pt) onto Au nanotriangles: effects of reductants and plasmonic properties.

Nanoscale

Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University, Princetonplein 5, 3584 CC Utrecht, The Netherlands.

Published: February 2021

The surface plasmon resonance of noble metals can be tuned by morphology and composition, offering interesting opportunities for applications in biomedicine, optoelectronics, photocatalysis, photovoltaics, and sensing. Here, we present the results of the symmetrical and asymmetrical overgrowth of metals (Ag, Pd, and Pt) onto triangular Au nanoplates using l-ascorbic acid (AA) and/or salicylic acid (SA) as reductants. By varying the reaction conditions, various types of Au nanotriangle-metal (Au NT-M) hetero-nanostructures were easily prepared. The plasmonic properties of as-synthesized nanoparticles were investigated by a combination of optical absorbance measurements and Finite-Difference Time-Domain (FDTD) simulations. We show that specific use of these reductants enables controlled growth of different metals on Au NTs, yielding different morphologies and allowing manipulation and tuning of the plasmonic properties of bimetallic Au NT-M (Ag, Pd, and Pt) structures.

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http://dx.doi.org/10.1039/d0nr06789jDOI Listing

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